Synthesis and X-Ray Crystal Structure of Two Novel Complexes: [MII(phen)3]2V4O12·phen·22H2O(MII=Co, Ni; phen=phenanthroline)

被引：0
|
作者：
L’udmila Žúrková
Renáta Kucsera
Róbert Gyepes
Michal Sivák
机构：
[1] Department of Inorganic Chemistry,
[2] Faculty of Natural Sciences,undefined
[3] Comenius University,undefined
[4] SK-84215,undefined
[5] Bratislava,undefined
[6] Slovak Republic,undefined
[7] Department of Inorganic Chemistry,undefined
[8] Faculty of Natural Sciences,undefined
[9] Charles University,undefined
[10] CS-12800,undefined
[11] Praha,undefined
[12] Czech Republic,undefined
来源：
Monatshefte für Chemie / Chemical Monthly | 2003年 / 134卷
关键词：
Keywords. Inorganic–organic hybrid materials; X-ray structure determination.;
D O I：
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学科分类号：
摘要：
 Two novel compounds, [Co(phen)3]2V4O12·phen·22H2O (1) and [Ni(phen)3]2 V4O12·phen·22H2O (2), were prepared from KVO3–1,10-phenanthroline (phen)–Co(NO3)2, resp. NiCl2–H2O reaction systems. The compounds 1 and 2 are isomorphous and crystallize in triclinic system, space group P-1. Their crystal structures are formed by two types of layers parallel to 001: a cationic one consisting of [MII(phen)3]2+ ions and an anionic one containing the cyclic V4O124− anions. The solvate phenanthroline and crystal water molecules are located in the cationic and anionic layers, respectively. The IR spectra of 1 and 2 are consistent with the presence of the cyclic V4O124− anions in the complexes.
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页码：1071 / 1079
页数：8
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