Synthesis of N,N′-di(tert-butyl)bispidin-9-ones

被引：0
|
作者：
A. I. Kuznetsov
I. M. Senan
T. M. Serova
机构：
[1] M. V. Lomonosov Moscow State University of Fine Chemical Technologies,Institute of Physiologically Active Compounds
[2] Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2012年 / 61卷
关键词：
bispidine; 3,7-diazabicyclo[3.3.1]nonane; condensation; acetone; ethyl methyl ketone; diethyl ketone; 1,3,5-tri(; -butyl)-1,3,5-triazacyclohexane; 3,7-di(; -butyl)bispidin-9-one derivatives; 3,7-di(; -butyl)-3,7-diazabicyclo[3.3.1]nonan-9-one derivatives;
D O I：
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学科分类号：
摘要：
Condensation of 1,3,5-tri(tert-butyl)-1,3,5-triazacyclohexane with acetone gave 3,7-di(tert-butyl)-1,5-bis[(tert-butylamino)methyl]bispidin-9-one. Reactions with ethyl methyl ketone and other ketones of the formula RCH2COCH3 yielded 5-R-3,7-di(tert-butyl)-1-[(tert-butylamino)methyl]bispidin-9-ones, while reactions with diethyl ketone and other symmetrical ketones of the formula RCH2COCH2R afforded 1,5-R-3,7-di(tert-butyl)bispidin-9-ones.
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页码：308 / 312
页数：4
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