Synthesis of anatase TiO2 with exposed {001} and {101} facets and photocatalytic activity

被引:0
|
作者
Jia Sun
Ming Zhang
Zhi-Feng Wang
Hai-Yan Chen
Ye Chen
Naoya Murakami
Teruhisa Ohno
机构
[1] Yangzhou University,School of Chemistry and Chemical Engineering
[2] Yangzhou University,Testing Center
[3] Yangzhou Polytechnic Institute,Department of Chemical Engineering
[4] Kyushu Institute of Technology,Department of Applied Chemistry, Faculty of Engineering
[5] Japan Science and Technology Agency,undefined
来源
Rare Metals | 2019年 / 38卷
关键词
Anatase; {001} and {101} facets; H; O; –NH;
D O I
暂无
中图分类号
学科分类号
摘要
Anatase titanium(IV) oxide (TiO2) particles with exposed {001} and {101} facets were prepared by hydrothermal treatment of amorphous TiO2 with H2O2–NH3 solution. Crystal phase, shape, and size of TiO2 particles are found to be greatly dependent on the ratio of H2O2–NH3 solution. The prepared TiO2 particles with specific exposed crystal faces show higher photocatalytic activity for acetaldehyde decomposition than commercial spherical TiO2 particles. This result implies that recombination is prevented by spatial separation of redox sites in the particles because of selective migration of electrons and positive holes to specific exposed crystal faces and/or different reactivity of electrons and positive holes on the specific exposed crystal face.
引用
收藏
页码:287 / 291
页数:4
相关论文
共 50 条
  • [41] Tunable Photocatalytic Selectivity of Hollow TiO2 Microspheres Composed of Anatase Polyhedra with Exposed {001} Facets
    Liu, Shengwei
    Yu, Jiaguo
    Jaroniec, Mietek
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (34) : 11914 - 11916
  • [42] Synthesis of anatase TiO2 with exposed (100) facets and enhanced electrorheological activity
    He, Kai
    Wen, Qingkun
    Wang, Chengwei
    Wang, Baoxiang
    Yu, Shoushan
    Hao, Chuncheng
    Chen, Kezheng
    [J]. SOFT MATTER, 2017, 13 (43) : 7879 - 7889
  • [43] Solvothermal fabrication of TiO2/sepiolite composite gel with exposed {001) and {101) facets and its enhanced photocatalytic activity
    Liu, Ruirui
    Ji, Zhijiang
    Wang, Jing
    Zhang, Jinjun
    [J]. APPLIED SURFACE SCIENCE, 2018, 441 : 29 - 39
  • [44] Synthesis of octagonal microdisks assembled from anatase TiO2 nanosheets with exposed {001} facets
    Hu, XiaoYi
    [J]. CERAMICS INTERNATIONAL, 2014, 40 (09) : 15033 - 15043
  • [45] Microwave-assisted rapid synthesis of anatase TiO2 nanocrystals with exposed {001} facets
    Zheng, Yang
    Lv, Kangle
    Wang, Zhouyou
    Deng, Kejian
    Li, Mei
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2012, 356 : 137 - 143
  • [46] Anatase TiO2 hollow microspheres with exposed {001} facets: Facile synthesis and enhanced photocatalysis
    Wang, Xiaoliang
    He, Huanlong
    Chen, Yan
    Zhao, Jinqiu
    Zhang, Xiangyi
    [J]. APPLIED SURFACE SCIENCE, 2012, 258 (15) : 5863 - 5868
  • [47] Synthesis and Photocatalytic Activity of TiO2/CdS Nanocomposites with Co-Exposed Anatase Highly Reactive Facets
    Du, Yi-en
    Niu, Xianjun
    He, Xinru
    Hou, Kai
    Liu, Huiling
    Zhang, Caifeng
    [J]. MOLECULES, 2021, 26 (19):
  • [48] Effect of substrate on evaluation of the photocatalytic activity of TiO2 nanocrystals with exposed {001} facets
    Ye, Hengpeng
    Lu, Shaoming
    [J]. APPLIED SURFACE SCIENCE, 2013, 270 : 741 - 745
  • [49] Outstanding antibacterial performance of bipyramidal anatase TiO2 with {101}-exposed facets
    Chan, Kuei-Lin
    Lee, Chi-Young
    Chiu, Hsin-Tien
    Chen, Jui-Yi
    Li, Cheng-Yu
    Lin, Wei-Hsiang
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [50] Hierarchical TiO2 Microspheres: Synergetic Effect of {001} and {101} Facets for Enhanced Photocatalytic Activity
    Zheng, Zhaoke
    Huang, Baibiao
    Lu, Jibao
    Qin, Xiaoyan
    Zhang, Xiaoyang
    Dai, Ying
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (52) : 15032 - 15038