Kinetics and mechanism of radiation telomerization of tetrafluoroethylene in hexafluoropropan-2-ol and trifluoroethanol

被引：0

作者：

G. A. Kichigina

P. P. Kushch

D. P. Kiryukhin

S. I. Kuzina

A. I. Mikhailov

机构：

[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics

来源：

Russian Chemical Bulletin | 2017年 / 66卷

关键词：

tetrafluoroethylene; telomer; radiation-chemical synthesis; fluorinated solvents;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The kinetics of radiation telomerization of tetrafluoroethylene (TFE) in trifluoroethanol and hexafluoropropan-2-ol (HFIP) has been investigated by method of kinetic calorimetry. The nature of active centers initiating the process of telomerization of tetrafluoroethylene in hexafluoroisopropanol in the temperature range of 77—300 K was investigated by ESR spectroscopy. The molecular structure and properties of the obtained telomeres were studied by IR spectroscopy and TGA.

引用

页码：468 / 473

页数：5

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