Kinetics and mechanism of radiation telomerization of tetrafluoroethylene in hexafluoropropan-2-ol and trifluoroethanol

被引：0
|
作者：
G. A. Kichigina
P. P. Kushch
D. P. Kiryukhin
S. I. Kuzina
A. I. Mikhailov
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Chemical Bulletin | 2017年 / 66卷
关键词：
tetrafluoroethylene; telomer; radiation-chemical synthesis; fluorinated solvents;
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学科分类号：
摘要：
The kinetics of radiation telomerization of tetrafluoroethylene (TFE) in trifluoroethanol and hexafluoropropan-2-ol (HFIP) has been investigated by method of kinetic calorimetry. The nature of active centers initiating the process of telomerization of tetrafluoroethylene in hexafluoroisopropanol in the temperature range of 77—300 K was investigated by ESR spectroscopy. The molecular structure and properties of the obtained telomeres were studied by IR spectroscopy and TGA.
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页码：468 / 473
页数：5
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