Hydrogen Ion-Selective Poly(vinyl chloride) Membrane Electrode Based on a Calix[4]arene

被引：0
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作者：
Demet Kuruoğlu
Esin Canel
Shahabuddin Memon
Mustafa Yilmaz
Esma Kiliç
机构：
[1] Ankara University,Department of Chemistry, Faculty of Science
[2] Selçuk University,Department of Chemistry
来源：
Analytical Sciences | 2003年 / 19卷
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摘要：
A hydrogen ion-selective poly(vinyl chloride) membrane electrode was constructed using 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetracyanomethoxycalix[4]arene as a neutral carrier. The electrode showed an apparent Nernstian response in the 2 - 11.5 pH range with a slope of 54.0±0.2 mV/pH at 20±1°C. This electrode showed a rapid response of the emf to changes in the pH, high ion selectivity with respect to lithium, sodium and potassium, and characteristics similar to those reported for the conventional pH glass membrane electrode. It can be used as a potentiometric indicator electrode in hydrofluoric acid solutions. The effects of iodide, thiocyanate, perchlorate and bromide on the characteristics of the electrode were also considered.
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页码：217 / 221
页数：4
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