Spectral study of reactions of La@C82 and Y@C82 with amino-containing solvents

被引：0
|
作者：
S. P. Solodovnikov
B. L. Tumanskii
V. V. Bashilov
S. F. Lebedkin
V. I. Sokolov
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
[2] Institute of Nuclear Solid State Physics,Karlsruhe Research Center
来源：
Russian Chemical Bulletin | 2001年 / 50卷
关键词：
endohedral metallofullerenes; ESR spectroscopy; reduction; amino-containing solvents; electronic absorption spectra;
D O I：
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中图分类号：
学科分类号：
摘要：
A solvent effect on the electronic absorption UV-VIS and ESR spectra of La@C82 and Y@C82 was found. The UV-VIS spectra of La@C82 in pyridine, dimethylformamide, and hexamethylphosphorotriamide are identical with that of the La@C82– anion, which is evidence for La@C82 reduction in these solvents. In amino-containing solvents, the shape of the ESR spectra depends on the temperature and the time of preparation of the solutions. Changes in the ESR spectra of La@C82 and Y@C82 in dimethylformamide are due to functionalization of these compounds upon reduction.
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页码：2242 / 2244
页数：2
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