Supramolecular motifs in liquids. Aqueous solutions of organic substances

被引：0
|
作者：
O. V. Grineva
机构：
[1] Lomonosov State University,
来源：
Journal of Structural Chemistry | 2006年 / 47卷
关键词：
structure; condensed phases; supramolecular motifs; aqueous solutions; framework of cooperative hydrogen bonds;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Different approaches to the analysis of the structure of condensed phases are briefly discussed. Introduced definition of the term “supramolecular motif” makes it possible to use this notion as a basis for finding correlations between structural peculiarities of the investigated systems and their properties. It is shown that the study of temperature dependences of the temperature coefficient of compressibility is a convenient way of detecting supramolecular motif (namely, framework of cooperative hydrogen bonds) in dilute aqueous solutions of organic substances.
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页码：186 / 193
页数：7
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