Reactions of 8-methyl-5-methylsulfanylmethyl-3-thiabicyclo-[3.3.1]non-7-en-6-one at the carbonyl group

被引：0
|
作者：
L. A. Baeva
A. D. Ulendeeva
A. A. Fatykhov
N. K. Lyapina
机构：
[1] Russian Academy of Sciences,Institute of Organic Chemistry, Ufa Research Center
来源：
Russian Journal of Organic Chemistry | 2010年 / 46卷
关键词：
Oxime; Hydroxylamine Hydrochloride; Allyl Alcohol; Aluminum Hydride; Saturated Alcohol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reduction of 8-methyl-5-methylsulfanylmethyl-3-thiabicyclo[3.3.1]non-7-en-6-one with aluminum hydride, lithium tetrahydridoaluminate, or lithium tris(tert-butoxy)hydridoaluminate in tetrahydrofuran gave 8-methyl-5-methylsulfanylmethyl-3-thiabicyclo[3.3.1]non-7-en-6-ol. 8-Methyl-5-methylsulfanylmethyl-3-thiabicyclo[3.3.1]nonan-6-ol was obtained by reduction of the title compound with sodium tetrahydridoborate in pyridine or dimethylformamide. The reaction of 8-methyl-5-methylsulfanylmethyl-3-thiabicyclo[3.3.1]non-7-en-6-one with hydroxylamine hydrochloride afforded the corresponding oxime.
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页码：1066 / 1069
页数：3
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