Studying the Initial Stage of Nucleation and Growth of a New Phase during Cathodic Intercalation of Lithium into Aluminum

被引：0
|
作者：
V. E. Guterman
L. N. Mironova
V. V. Ozeryanskaya
O. E. Saenko
机构：
[1] Rostov State University,
来源：
Russian Journal of Electrochemistry | 2001年 / 37卷
关键词：
Aluminum; Experimental Data; Physical Chemistry; Lithium; Intermetallic Compound;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Kinetics of cathodic intercalation of lithium into aluminum from a 0.5 M LiCl solution in dimethylformamide at the stage of nucleation and growth of intermetallic compound β-LiAl is studied by one- and two-pulse potentiostatic methods. If the length of the first potential pulse is short, the current at the beginning of the second pulse is proportional to the overvoltage squared. The experimental data point to a lamellar-spiral growth of β-LiAl crystals at the initial stage of their development and to a change in the balance between different growth mechanisms as a function of the overvoltage and surface coverage by β-LiAl.
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页码：57 / 62
页数：5
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