Synthesis and characterisation of 1,3-bis(2-benzimidazyl)-2-thiapropane, 1,5-bis(2-benzimidazyl)-3-thiapentane ligands and their PdCl2 complexes

被引：0
|
作者：
Naz M. Aghatabay
A. Baykal
M. Somer
机构：
[1] Fatih University,Department of Chemistry, Faculty of Arts and Sciences
[2] Buyukcekmece,Department of Chemistry
[3] Koc University,undefined
[4] Rumelifeneri Yolu,undefined
[5] Sariyer,undefined
来源：
Transition Metal Chemistry | 2004年 / 29卷
关键词：
Nitrogen; Sulphur; Physical Chemistry; Analytical Data; Inorganic Chemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The 1,3-bis(2-benzimidazyl)-2-thiapropane (TP2) and 1,5-bis(2-benzimidazyl)-3-thiapentane (TP3) ligands form 5-coordinate square pyramidal monometallic complexes with PdCl2. In both complexes the ligands act as chelating tridentate, through two of the nitrogen atoms in the imidazole ring and the sulphur atom of the bridging group. The ligands and complexes were characterised by analytical data and by modern spectroscopic methods such as FT-Raman, i.r., 1H and 13C-n.m.r. spectra.
引用
收藏
页码：159 / 163
页数：4
相关论文
共 50 条
  • [31] Synthesis and Crystal Structures of Dinuclear Cobalt(III) Complexes with 1,3-Bis(5-nitrosalicylideneamino)-2-propanol and 1,3-Bis(3-nitrosalicylideneamino)-2-propanol
    Mikuriya, Masahiro
    Naka, Yuko
    Yoshioka, Daisuke
    Handa, Makoto
    X-RAY STRUCTURE ANALYSIS ONLINE, 2016, 32 : 55 - 58
  • [32] Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp=1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)
    de Leon, Antonio
    Pons, Josefina
    Garcia-Anton, Jordi
    Solans, Xavier
    Font-Bardia, Merce
    Ros, Josep
    INORGANICA CHIMICA ACTA, 2009, 362 (10) : 3801 - 3806
  • [33] V-shaped ligand 1,3-bis(1-ethylbenzimidazol-2-yl)-2-thiapropane and manganese(II), cobalt(II) and copper(II) complexes: Synthesis, crystal structure, DNA-binding properties and antioxidant activities
    Wu, Huilu
    Yang, Zaihui
    Wang, Fei
    Peng, Hongping
    Zhang, Han
    Wang, Cuiping
    Wang, Kaitong
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 2015, 148 : 252 - 261
  • [34] SYNTHESIS OF "2,5-BIS(PIPERIDINOMETHYL)PIPERIDINE AND 1,5-BIS(AMINOMETHYL)-3-AZABICYCLO[3.2.1]OCTANONES
    AFSAH, EM
    METWALLY, MA
    KHALIFA, MM
    MONATSHEFTE FUR CHEMIE, 1984, 115 (03): : 303 - 307
  • [35] HYDROLYSIS OF 1,3-BIS(DIMETHYLCHLOROSILYL)-2,2,4,4-TETRAMETHYLCYCLODISILAZANE AND 1,3-BIS(DIMETHYLAMINOSILYL)-2,2,4,4-TETRAMETHYLCYCLODISILAZANE
    VAREZHKIN, YM
    ZHINKIN, DY
    MORGUNOVA, MM
    BOCHKAREV, VN
    ZHURNAL OBSHCHEI KHIMII, 1975, 45 (11): : 2455 - 2459
  • [36] Copper(II) complexes with 1,5-bis(2-hydroxybenzaldehyde) carbohydrazone
    Dragancea, Diana
    Shova, Sergiu
    Enyedy, Eva A.
    Breza, Martin
    Rapta, Peter
    Carrella, Luca M.
    Rentschler, Eva
    Dobrov, Anatolie
    Arion, Vladimir B.
    POLYHEDRON, 2014, 80 : 180 - 192
  • [37] An efficient synthesis of 1,3-bis(1,4,7-triazacyclonon-1-yl)-2-hydroxypropane, [1,3-bis(TACN)-2-propanol]
    Florio, P.
    Campi, E. M.
    Potdar, M. K.
    Jackson, W. R.
    Hearn, M. T. W.
    GREEN CHEMISTRY LETTERS AND REVIEWS, 2012, 5 (03) : 251 - 254
  • [38] 1,5-BIS(2-ISOPROPYLPHENYL)-1,5-DIPHENYLPENTATETRAENE
    HERRATH, MV
    REWICKI, D
    JUSTUS LIEBIGS ANNALEN DER CHEMIE, 1977, (04): : 582 - 587
  • [39] 1,5-Bis(2-methylphenyl)-3-nitroformazan
    von Eschwege, Karel G.
    Hosten, Eric C.
    Muller, Alfred
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : O425 - U841
  • [40] 1,5-bis(2-formylphenoxy)-3-oxapentane
    Dionysio, Nivea C. F.
    Bordinhao, Jairo
    Visentin, Lorenzo do Canto
    Ronconi, Celia Machado
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O546 - U717
12345