Synthesis and characterisation of 1,3-bis(2-benzimidazyl)-2-thiapropane, 1,5-bis(2-benzimidazyl)-3-thiapentane ligands and their PdCl2 complexes

被引：0
|
作者：
Naz M. Aghatabay
A. Baykal
M. Somer
机构：
[1] Fatih University,Department of Chemistry, Faculty of Arts and Sciences
[2] Buyukcekmece,Department of Chemistry
[3] Koc University,undefined
[4] Rumelifeneri Yolu,undefined
[5] Sariyer,undefined
来源：
Transition Metal Chemistry | 2004年 / 29卷
关键词：
Nitrogen; Sulphur; Physical Chemistry; Analytical Data; Inorganic Chemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The 1,3-bis(2-benzimidazyl)-2-thiapropane (TP2) and 1,5-bis(2-benzimidazyl)-3-thiapentane (TP3) ligands form 5-coordinate square pyramidal monometallic complexes with PdCl2. In both complexes the ligands act as chelating tridentate, through two of the nitrogen atoms in the imidazole ring and the sulphur atom of the bridging group. The ligands and complexes were characterised by analytical data and by modern spectroscopic methods such as FT-Raman, i.r., 1H and 13C-n.m.r. spectra.
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页码：159 / 163
页数：4
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