Effects of the Nature of Transition Metal on the Composition and Structure of Reaction Products of M[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 (М = Cu(II), Ni(II), Co(II), or Mn(II)) with 1,10-Phenanthroline

被引：0

作者：

A. A. Grineva

M. A. Uvarova

R. R. Datchuk

S. E. Nefedov

机构：

[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry

来源：

Russian Journal of Inorganic Chemistry | 2018年 / 63卷

关键词：

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Reactions of M[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 (M = Ni(II), Co(II), or Mn(II)) adducts with 1,10-phenanthroline in chloroform at room temperature are found to yield complexes PhennM[(OOCC5H4) Mn(CO)3]2 (Co(II) or Mn(II), n = 2; M = Ni(II), n = 3). A similar reaction of dimeric Cu2[μ-(OOCC5H4) Mn(CO)3]4[O(H)Me]2 yields mononuclear PhenCu[(OOCC5H4)Mn(CO)3][O(H)Me] · MeOH. The resulting complexes are isolated in high yields and characterized by chemical analysis, IR spectroscopy, and X-ray crystallography.

引用

页码：610 / 617

页数：7

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