Synthesis and properties of copper(II) complexes with a chiral dioxatetraazamacrocyclic ligand based on a natural monoterpene, (+)-3-carene

被引：0
|
作者：
S. V. Larionov
L. I. Myachina
L. A. Sheludyakova
E. G. Boguslavskii
S. N. Bizyaev
A. V. Tkachev
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Russian Academy of Sciences,Vorozhtsov Institute of Organic Chemistry, Siberian Division
来源：
Russian Journal of Inorganic Chemistry | 2007年 / 52卷
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摘要：
The copper(II) compounds [CuL](NO3)2 · H2O (I), [CuL](ClO4)2 · H2O (II), CuLCl2 · 3H2O (III), and CuLBr2 · 4H2O (IV), where L is a chiral dioxatetraazamacrocyclic ligand based on the natural monoterpene (+)-3-carene, have been synthesized. According to IR and EPR spectroscopy, L acts as a tetradentate chelating ligand coordinated through the N atoms of the NH and C=N groups. The NO3− anions in I and the ClO4− anions in II are outer-sphere. I and II have a planar coordination core CuN4, III has a CuN4ClO coordination core, and IV has a CuN4Br2 coordination core.
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页码：42 / 45
页数：3
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