Study of the Ternary Systems M(II)(NO3)2–LiNO3–H2O (M(II) 5 Mg, Ca, Sr, Ba) at 25°C

被引：0
|
作者：
Vladimír Zbranek
Jitka Eysseltová
机构：
[1] Department of Inorganic Chemistry,
[2] Faculty of Science,undefined
[3] Charles University,undefined
[4] CZ-12840 Prague,undefined
[5] Czech Republic,undefined
来源：
Monatshefte für Chemie / Chemical Monthly | 2001年 / 132卷
关键词：
Keywords. Crystallization; Hydration analysis; Lithium nitrate; Solubility.;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
 The isothermal solubility diagrams of four aqueous systems containing lithium nitrate and nitrates of group IIA metals – magnesium, calcium, strontium, and barium – were studied at 25°C. No double salt formation was observed. The results were compared with similar nitrate and chloride systems. Some trends in the shape of the phase diagrams were observed. Hydration analysis was applied to the solubility branches, rendering information about ionic processes in saturated solutions. Further, the ratio of activity coefficients of the saturating solid phase in ternary and binary solutions (γ/γ0) was obtained.
引用
收藏
页码：1463 / 1475
页数：12
相关论文
共 50 条
  • [1] Study of the ternary systems M(II)(NO3)2-LiNO3-H2O (M(II) = Mg, Ca, Sr, Ba) at 25°C
    Zbranek, V
    Eysseltová, J
    MONATSHEFTE FUR CHEMIE, 2001, 132 (12): : 1463 - 1475
  • [2] M(NO3)-PR(NO3)3-H2O(M-MG,SR,BA) SYSTEMS AT 25-50-DEGREES-C
    SHEVCHUK, VG
    BUNYAKINA, NV
    DRYUCHKO, AG
    STOROZHENKO, DA
    ZHURNAL NEORGANICHESKOI KHIMII, 1985, 30 (03): : 801 - 803
  • [3] (LINO3)2-(KNO3)2-SR(NO3)2 AND (LINO3)2-CA(NO3)2-SR(NO3)2 SYSTEMS
    ILYASOV, II
    PALOBEKOV, AG
    GANTSOV, SK
    ZHURNAL NEORGANICHESKOI KHIMII, 1980, 25 (06): : 1711 - 1712
  • [4] STUDY OF THE LINO3-CA(NO3)2-BA(NO3)2 AND LINO3-SR(NO3)2-BA(NO3)2 SYSTEMS
    ILYASOV, II
    DUNAEVA, TI
    LEPESHKOV, IN
    ZHURNAL NEORGANICHESKOI KHIMII, 1980, 25 (08): : 2295 - 2297
  • [5] Phase diagram of the system KNO3 + LiNO3 + Mg(NO3)2 + H2O
    Yin, Xia
    Chen, Qiyuan
    Zeng, Dewen
    Wang, Wenlei
    CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2011, 35 (04): : 463 - 472
  • [6] The system Ca(NO3),-Sr(NO3),-H2O at 25 and 60 degrees
    Kobe, KA
    Stewart, PB
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 : 1301 - 1303
  • [7] Elastic and Photoelastic Properties of M(NO3)2, MO (M = Mg, Ca, Sr, Ba)
    Zhuravlev, Yu. N.
    Korabel'nikov, D. V.
    RUSSIAN PHYSICS JOURNAL, 2017, 60 (01) : 149 - 156
  • [8] Elastic and Photoelastic Properties of M(NO3)2, MO (M = Mg, Ca, Sr, Ba)
    Yu. N. Zhuravlev
    D. V. Korabel’nikov
    Russian Physics Journal, 2017, 60 : 149 - 156
  • [9] SATURATED SOLUTIONS OF M(NO3)2-H2O-CH3OH (M=SR, BA) SYSTEMS
    STOEV, MD
    ROBLEDO, JMA
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1994, 59 (06) : 1342 - 1348
  • [10] Investigation of low-hydrated metal(II) nitrates. Syntheses and crystal structures of Zn(NO3)2 • H2O and M(II)(NO3)2 • 2 H2O (M = Mg, Mn, Co, Ni)
    Wildner, Manfred
    Giester, Gerald
    Lengauer, Christian L.
    Zemann, Josef
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2012, 227 (03): : 129 - 140
12345