Study of the ternary systems M(II)(NO3)2-LiNO3-H2O (M(II) = Mg, Ca, Sr, Ba) at 25°C

被引：11
|
作者：
Zbranek, V [1 ]
Eysseltová, J [1 ]
机构：
[1] Charles Univ, Fac Sci, Dept Inorgan Chem, CZ-12840 Prague, Czech Republic
来源：
MONATSHEFTE FUR CHEMIE | 2001年 / 132卷 / 12期
关键词：
crystallization; hydration analysis; lithium nitrate; solubility;
D O I：
10.1007/s007060170003
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The isothermal solubility diagrams of four aqueous systems containing lithium nitrate and nitrates of group IIA metals - magnesium, calcium, strontium, and barium - were studied at 25degreesC. No double salt formation was observed. The results were compared with similar nitrate and chloride systems. Some trends in the shape of the phase diagrams were observed. Hydration analysis was applied to the solubility branches, rendering information about ionic processes in saturated solutions. Further, the ratio of activity coefficients of the saturating solid phase in ternary and binary solutions (gamma/gamma(0)) was obtained.
引用
收藏
页码：1463 / 1475
页数：13
相关论文
共 50 条
  • [1] Study of the Ternary Systems M(II)(NO3)2–LiNO3–H2O (M(II) 5 Mg, Ca, Sr, Ba) at 25°C
    Vladimír Zbranek
    Jitka Eysseltová
    Monatshefte für Chemie / Chemical Monthly, 2001, 132 : 1463 - 1475
  • [2] M(NO3)-PR(NO3)3-H2O(M-MG,SR,BA) SYSTEMS AT 25-50-DEGREES-C
    SHEVCHUK, VG
    BUNYAKINA, NV
    DRYUCHKO, AG
    STOROZHENKO, DA
    ZHURNAL NEORGANICHESKOI KHIMII, 1985, 30 (03): : 801 - 803
  • [3] State of the components and structural transitions in the ternary system Ca(NO3)2-LiNO3-H2O
    Khripun, MK
    Chervonenko, KY
    Efimov, AY
    Khripun, VD
    Kiselev, AA
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2000, 70 (02) : 200 - 205
  • [4] STUDY OF THE LINO3-CA(NO3)2-BA(NO3)2 AND LINO3-SR(NO3)2-BA(NO3)2 SYSTEMS
    ILYASOV, II
    DUNAEVA, TI
    LEPESHKOV, IN
    ZHURNAL NEORGANICHESKOI KHIMII, 1980, 25 (08): : 2295 - 2297
  • [5] Solubility Phase Diagram of the Ca(NO3)2-LiNO3-H2O System
    Jiang, Juan
    Yin, Xia
    Li, Dongdong
    Tan, Yuqi
    Zeng, Dewen
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (03): : 1125 - 1130
  • [6] Elastic and Photoelastic Properties of M(NO3)2, MO (M = Mg, Ca, Sr, Ba)
    Zhuravlev, Yu. N.
    Korabel'nikov, D. V.
    RUSSIAN PHYSICS JOURNAL, 2017, 60 (01) : 149 - 156
  • [7] Elastic and Photoelastic Properties of M(NO3)2, MO (M = Mg, Ca, Sr, Ba)
    Yu. N. Zhuravlev
    D. V. Korabel’nikov
    Russian Physics Journal, 2017, 60 : 149 - 156
  • [8] SATURATED SOLUTIONS OF M(NO3)2-H2O-CH3OH (M=SR, BA) SYSTEMS
    STOEV, MD
    ROBLEDO, JMA
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1994, 59 (06) : 1342 - 1348
  • [9] LN(NO3)3-M(NO3)2-H2O SYSTEMS AT 25 DEGREES C
    YAKIMOV, MA
    GUZHAVIN.EI
    ZHURNAL NEORGANICHESKOI KHIMII, 1971, 16 (02): : 507 - &
  • [10] DUCTILITY OF FUSED KNO3-M(NO3)2, (M-CA, SR, BA) SYSTEMS
    PROTSENK.PI
    SMOTRAKO.VG
    POPOVSKA.NP
    ZHURNAL PRIKLADNOI KHIMII, 1972, 45 (12) : 2745 - 2747
12345