NMR Study of Reactions between Pd, Ru, and Rh Nitrite Complexes with Sulfamic Acid

被引：0
|
作者：
A. V. Belyaev
V. A. Emel'yanov
S. P. Khranenko
M. A. Fedotov
机构：
[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Division
来源：
Russian Journal of Coordination Chemistry | 2001年 / 27卷
关键词：
Physical Chemistry; Nitrite; Chemical Shift; Predominant Form; Sulfamate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Reactions of nitrite complexes of Pd, Ru, and Rh with sulfamic acid were studied by the 14, 15N, and 17O NMR method. Chemical shifts were assigned, and the predominant forms of the complexes were established. The reaction products at room temperature are cis-nitroaqua complexes. Coordination of the sulfamate ion upon storage for a long time or on heating was detected.
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页码：184 / 194
页数：10
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