Two-dimensional to three-dimensional transition of tungsten clusters anchored on graphite surface

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作者
Tetsuichiro Hayakawa
Hisato Yasumatsu
机构
[1] Genesis Research Institute,East Tokyo Laboratory
[2] Inc.,Cluster Research Laboratory, Toyota Technological Institute: In East Tokyo Laboratory
[3] Genesis Research Institute,undefined
[4] Inc.,undefined
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Tungsten clusters; Supported clusters; STM; Graphite; Monatomic-layered cluster disk;
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摘要
Experimental studies have been performed on unisize tungsten clusters constructed on a graphite surface by means of the scanning tunneling microscopy. It was found that the geometry of the clusters changes instantaneously from a monatomic-layer tungsten disk to a diatomic-layer structure between the cluster size of 10 and 11. We concluded that this transition is driven by a change in the dominant interaction from the attractive electrostatic interaction between the cluster and the surface to intracluster cohesive metallic interaction.
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