Spectroscopic and model studies of the Ni-Fe hydrogenase reaction mechanism

被引:0
|
作者
Michael J. Maroney
Peter A. Bryngelson
机构
[1] Department of Chemistry,
[2] University of Massachusetts,undefined
[3] Amherst,undefined
[4] MA 01003-4510,undefined
来源
JBIC Journal of Biological Inorganic Chemistry | 2001年 / 6卷
关键词
Ni-Fe hydrogenase X-ray absorption spectroscopy Extended X-ray absorption fine structure X-ray absorption near-edge structure Electron paramagnetic resonance;
D O I
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中图分类号
学科分类号
摘要
Ni-Fe H2ases exhibit a number of states that have been spectroscopically characterized. The structural information arising from these spectroscopic studies are compared with predictions from theoretical calculations and are used to address aspects of hydrogenase reaction mechanism.
引用
收藏
页码:453 / 459
页数:6
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