Synthesis, spectral and magnetic properties of binuclear copper(II)/nickel(II) and copper(II) complexes bridged by glyoximate groups

被引：0
|
作者：
Shu-zhong Zhan
Qing Dai
Chun-wei Yuan
机构：
[1] Southeast University,National Laboratory of Molecular and Biomolecular Electronics
来源：
Transition Metal Chemistry | 1999年 / 24卷
关键词：
Copper; Physical Chemistry; Nickel; Inorganic Chemistry; Catalysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Three new dinuclear complexes, [(tmen) (H2O)2Ni (Hdmg)(dmg)Cu]·ClO4, [(dien)(H2O)Ni (Hdmg)(dmg) Cu]·ClO4 and [(tmen)Cu(Hdmg)(dmg) Cu] ClO4·H2O (H2dmg=dimethylglyoxime, tmen=tetramethylene diamine), have been prepared. Variable-temperature- magnetic susceptibility measurements (75–300K) on the complexes reveal the presence of intramolecular antiferromagnetic interactions through the oximate bridges. The formation of mononuclear, dinuclear complexes has been confirmed by spectrophotometry.
引用
下载
收藏
页码：74 / 76
页数：2
相关论文
共 50 条
  • [21] MAGNETIC AND SPECTRAL STUDIES ON SOME BINUCLEAR COPPER(II) COMPLEXES
    SINGH, B
    SINGH, RN
    AGGARWAL, RC
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1985, 24 (06): : 518 - 520
  • [22] Direct synthesis and properties of binuclear copper(II) complexes
    Yang, RN
    Wang, DM
    Kuang, AY
    Liu, YF
    Jin, DM
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2001, 31 (09): : 1647 - 1662
  • [23] BINUCLEAR METAL-COMPLEXES .7. PREPARATION AND PROPERTIES OF BINUCLEAR COPPER(II) AND NICKEL(II) COMPLEXES OF HYDROGEN-BRIDGED MACROCYCLES
    OKAWA, H
    TOKII, T
    MUTO, Y
    KIDA, S
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1973, 46 (08) : 2464 - 2467
  • [24] Synthesis of unsymmetrical 'end-off' phenoxo and oximinato di bridged copper(II) and nickel(II) complexes: spectral, electrochemical and magnetic properties
    Saravanakumar, D
    Sengottuvelan, N
    Priyadarshni, G
    Kandaswamy, M
    Okawa, H
    POLYHEDRON, 2004, 23 (04) : 665 - 672
  • [25] Squarato-bridged nickel(II) and copper(II) complexes
    Massoud, Salah S.
    Mautner, Franz A.
    Vicente, Ramon
    Broussard, Kendra T.
    Landry, Kristen N.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 150 - 150
  • [26] μ-phenoxo-bridged binuclear copper(II) complexes
    Li, Wen-bao
    Zhuang, Ya-Hui
    Liao, Dai-zheng
    Wang, Geng-ling
    Transition Metal Chemistry, 1994, 19 (03):
  • [27] Binuclear and tetranuclear copper(II) complexes bridged by dimethylglyoxime
    Chen, XY
    Cheng, P
    Liu, XW
    Yan, SP
    Bu, WM
    Liao, DZ
    Jiang, ZH
    CHEMISTRY LETTERS, 2003, 32 (02) : 118 - 119
  • [28] SYNTHESIS AND CHARACTERIZATION OF IMIDAZOLATE-BRIDGED BINUCLEAR COPPER(II) COMPLEXES
    MATSUMOTO, N
    MURAKAMI, H
    AKUI, T
    HONBO, J
    OKAWA, H
    OHYOSHI, A
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (05) : 1609 - 1610
  • [29] SPECTRAL AND MAGNETIC PROPERTIES OF COPPER(II) PROPIONATE AND COPPER(II) MONOCHLOROACETATE COMPLEXES OF ETHYLENEDIAMINE
    MELNIK, M
    NASANEN, R
    SUOMEN KEMISTILEHTI, 1970, 43 (01): : 18 - &
  • [30] Electrochemical and spectral studies of binuclear monohydroxo-bridged copper(II) complexes
    Srivastava, Krishna
    Srivastava, Ashish Kumar
    Prasad, Jagdish
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2009, 86 (01) : 23 - 27
12345