Synthesis, spectral and magnetic properties of binuclear copper(II)/nickel(II) and copper(II) complexes bridged by glyoximate groups

被引：0

作者：

Shu-zhong Zhan

Qing Dai

Chun-wei Yuan

机构：

[1] Southeast University,National Laboratory of Molecular and Biomolecular Electronics

来源：

Transition Metal Chemistry | 1999年 / 24卷

关键词：

Copper; Physical Chemistry; Nickel; Inorganic Chemistry; Catalysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Three new dinuclear complexes, [(tmen) (H2O)2Ni (Hdmg)(dmg)Cu]·ClO4, [(dien)(H2O)Ni (Hdmg)(dmg) Cu]·ClO4 and [(tmen)Cu(Hdmg)(dmg) Cu] ClO4·H2O (H2dmg=dimethylglyoxime, tmen=tetramethylene diamine), have been prepared. Variable-temperature- magnetic susceptibility measurements (75–300K) on the complexes reveal the presence of intramolecular antiferromagnetic interactions through the oximate bridges. The formation of mononuclear, dinuclear complexes has been confirmed by spectrophotometry.

引用

页码：74 / 76

页数：2

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[1] Synthesis, spectral and magnetic properties of binuclear copper(II)/nickel(II) and copper(II) complexes bridged by glyoximate groups
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