Proton Conductivity of Cs2MnH3(P2O7)2 and Rb2MnHP2O7(H2PO4)2

被引：0
|
作者：
N. N. Chudinova
E. V. Murashova
B. S. Zakharova
V. A. Tarnopol'skii
A. B. Yaroslavtsev
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Inorganic Materials | 2004年 / 40卷
关键词：
Phosphate; Inorganic Chemistry; Structural Data; Proton Conductivity; Mixed Phosphate;
D O I：
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中图分类号：
学科分类号：
摘要：
Cs2MnH3(P2O7)2 and Rb2MnHP2O7(H2PO4)2 are shown to have an appreciable proton conductivity: 5 × 10–8 and 2 × 10–5 S/cm in the Cs compound at 298 and 400 K, respectively, and 10–7 and 4 × 10–7 S/cm in the Rb compound. The conductivity and structural data are analyzed in relation to the mechanisms of protonic conduction in these mixed phosphates.
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页码：277 / 280
页数：3
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