Conversion of Glycerol to Acrolein in the Presence of WO3/ZrO2 Catalysts

被引:6
|
作者
Arda Ulgen
Wolfgang Hoelderich
机构
[1] RWTH Aachen University,
来源
Catalysis Letters | 2009年 / 131卷
关键词
Glycerol (glycerin); Acrolein; Alcohol dehydration; Solid acid; WO; /ZrO; Sustainable technology;
D O I
暂无
中图分类号
学科分类号
摘要
Dehydration of glycerol to acrolein was performed on WO3/ZrO2 solid heterogeneous catalysts in a continuous flow fixed bed reactor. A maximum of 75% acrolein selectivity was achieved at 100% conversion of glycerol. The acrolein selectivity correlates with the concentration of weak acidic sites of the WO3/ZrO2 catalysts that were free of basic sites.
引用
收藏
页码:122 / 128
页数:6
相关论文
共 50 条
  • [21] Production of 1,3-propanediol by hydrogenolysis of glycerol catalyzed by Pt/WO3/ZrO2
    Kurosaka, Tadahiro
    Maruyama, Hideyuki
    Naribayashi, Ikuya
    Sasaki, Yoshiyuki
    CATALYSIS COMMUNICATIONS, 2008, 9 (06) : 1360 - 1363
  • [22] Isomerization of n-Heptane over Pt(Pd)/WO3/ZrO2 Catalysts
    Shkurenok, V. A.
    Smolikov, M. D.
    Yablokova, S. S.
    Kir'yanov, D. I.
    Belyi, A. S.
    OIL AND GAS ENGINEERING (OGE-2018), 2018, 2007
  • [23] Vapour-phase nitration of benzene over superacid WO3/ZrO2 catalysts
    Brei, VV
    Prudius, SV
    Melezhyk, OV
    APPLIED CATALYSIS A-GENERAL, 2003, 239 (1-2) : 11 - 16
  • [24] Features of the phase composition, acidity, and isomerization activity of Pt/WO3/ZrO2 catalysts
    M. D. Smolikov
    V. A. Shkurenok
    O. V. Dzhikiya
    D. I. Kir’yanov
    E. V. Zatolokina
    A. S. Belyi
    Russian Chemical Bulletin, 2020, 69 : 1714 - 1718
  • [25] Preparing and studying Pt/WO3/ZrO2 catalysts for the isomerization of n-heptane
    Smolikov M.D.
    Shkurenok V.A.
    Yablokova S.S.
    Kir’yanov D.I.
    Paukshtis E.A.
    Leont’eva N.N.
    Belyi A.S.
    Drozdov V.A.
    Smolikov, M.D. (smolikov@ihcp.ru), 1600, Maik Nauka Publishing / Springer SBM (09): : 54 - 61
  • [26] Characteristics of Pt/WO3/CeO2/ZrO2 Catalysts for catalytic reduction of NO by CO
    Zhu, Hai-ou
    Kim, Jeong-Rang
    Ihm, Son-Ki
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 86 (1-2) : 87 - 92
  • [27] Epoxidation of the polyisobutene using WO3/ZrO2 catalyst
    Li, Mei
    Chen, Zhiming
    RESEARCH ON CHEMICAL INTERMEDIATES, 2012, 38 (08) : 1921 - 1929
  • [28] Research progress of WO3/ZrO2 in alkane isomerization
    Chemistry and Chemical Engineering, Daqing Petroleum Institute, Daqing 163318, China
    不详
    Shiyou Xuebao Shiyou Jiagong, 2009, 2 (283-290):
  • [29] Epoxidation of the polyisobutene using WO3/ZrO2 catalyst
    Mei Li
    Zhiming Chen
    Research on Chemical Intermediates, 2012, 38 : 1921 - 1929
  • [30] WO3/ZrO2:: a potential catalyst for the acetylation of anisole
    Sakthivel, R
    Prescott, H
    Kemnitz, E
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 223 (1-2) : 137 - 142