Synthesis and Structural Characterisation of Two Copper(II) Complexes of N-(1-acetyl-2-propylidene) (2-pyridylmethyl) amine

被引：0
|
作者：
Ruma Karmakar
Chirantan Roy Choudhury
Andrei S. Batsanov
Stuart R. Batten
Samiran Mitra
机构：
[1] Jadavpur University,Department of Chemistry
[2] University of Durham,Department of Chemistry
[3] Monash University,School of Chemistry
来源：
Structural Chemistry | 2005年 / 16卷
关键词：
Crystal structure; copper(II); tetradentate Schiff base; bromide; isocyanate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two new complexes [CuBr(C11H13N2O)] (1) and [Cu(NCO)(C11H13N2O)] (2) containing the tridentate Schiff base ligand, N-(1-acetyl-2-propylidene)(2-pyridylmethyl) amine which is the 1:1 condensation product of acetylacetone and 2-aminomethylpyridine, have been synthesised and characterised by elemental analysis, IR and electronic spectra, electrochemical study and single crystal X-ray diffraction study. Crystal structures reveal that the copper atom in both the complexes are in square geometry formed by the N2O donor set of the Schiff base and a bromine atom in 1 and one cyanate ligand in 2. Both bromide and isocyanate ligands act in a terminal monodentate fashion.
引用
收藏
页码：535 / 539
页数：4
相关论文
共 50 条
  • [41] Copper(II) and Cadmium(II) Complexes Based on N,N-Bis(3, 5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine Ligand: Syntheses, Structures, Magnetic, and Luminescent Properties
    Yang, Lijuan
    Chen, Wenqian
    Chen, Yanmei
    Liu, Wei
    Lei, Tao
    Li, Lei
    Lin, Miaoshui
    Wu, Jian
    Cao, Yanyuan
    Li, Wu
    Li, Yahong
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (11): : 1833 - 1838
  • [42] Acetato(methanol)[N-phenyl-N,N-bis(2-pyridylmethyl)amine]copper(II) hexafluorophosphate
    Nielsen, A
    Bond, AD
    McKenzie, CJ
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M478 - M480
  • [43] Conformation Diversity of Complexes Constructed by N-(2-Pyridylmethyl)-phenylalanine and Zn(Ⅱ)
    李新发
    刘庆燕
    谢在来
    李涛海
    李亚峰
    曹荣
    Chinese Journal of Structural Chemistry, 2009, (01) : 53 - 60
  • [44] Conformation Diversity of Complexes Constructed by N-(2-Pyridylmethyl)-phenylalanine and Zn(Ⅱ)
    李新发
    刘庆燕
    谢在来
    李涛海
    李亚峰
    曹荣
    结构化学, 2009, 28 (01) : 53 - 60
  • [45] PALLADIUM(II) COMPLEXES OF N-(2-PYRIDYLMETHYL)-2-PYRIDYLACETAMIDE AND N-[2-(2-PYRIDYL)ETHYL]-2-PYRIDINECARBOXAMIDE
    NONOYAMA, M
    YAMASAKI, K
    NIPPON KAGAKU KAISHI, 1973, (10) : 1893 - 1895
  • [46] Chromium(II) and chromium(III) complexes supported by tris(2-pyridylmethyl)amine: Synthesis, structures, and reactivity
    Robertson, NJ
    Carney, MJ
    Halfen, JA
    INORGANIC CHEMISTRY, 2003, 42 (21) : 6876 - 6885
  • [47] Dichlorido[(S)-(1-phenylethyl)(2-pyridylmethyl)amine-κ2N,N′]zinc(II)
    Nguyen, Quang Trung
    Jeong, Jong Hwa
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M457 - U216
  • [48] Synthesis and characterization of mononuclear and dinuclear ruthenium complexes with tris(2-pyridylmethyl)amine and tris(5-methyl-2-pyridylmethyl)amine
    Kojima, T
    Amano, T
    Ishii, Y
    Ohba, M
    Okaue, Y
    Matsuda, Y
    INORGANIC CHEMISTRY, 1998, 37 (16) : 4076 - 4085
  • [49] Synthesis, structure, and magnetic properties of dicopper and tricobalt complexes based on N-(2-pyridylmethyl)iminodiethanol
    Shin, Jong Won
    Jeong, Ah Rim
    Hayami, Shinya
    Moon, Dohyun
    Min, Kil Sik
    INORGANIC CHEMISTRY FRONTIERS, 2015, 2 (08): : 763 - 770
  • [50] Synthesis, supramolecular assemblies and luminescence of nickel(II) complexes based on a series of N-(2-pyridylmethyl) amino acid derivatives
    Zhang, Qing-Qing
    Zhang, Zhi-Hui
    Qu, Bao-Hua
    Chen, Qun
    He, Ming-Yang
    INORGANICA CHIMICA ACTA, 2014, 418 : 59 - 65
12345