Effect of hydrostatic pressure, temperature, and solvent on the rate of the Diels–Alder reaction between 9,10-anthracenedimethanol and maleic anhydride

被引：0
|
作者：
V. D. Kiselev
D. A. Kornilov
O. V. Anikin
L. I. Latypova
A. I. Konovalov
机构：
[1] Kazan Federal University,Arbuzov Institute of Organic and Physical Chemistry
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of Physical Chemistry A | 2017年 / 91卷
关键词：
9,10-dimetahnol anthracene; Diels–Alder reaction; effect of temperature; effect of pressure; solvent effect;
D O I：
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摘要：
The rate of the reaction between 9,10-anthracenedimethanol and maleic anhydride in 1,4-dioxane, acetonitrile, trichloromethane, and toluene is studied at 25, 35, 45°C in the pressure range of 1–1772 bar. The rate constants, enthalpies, entropies and activation volumes are determined. It is shown that the rate of reaction with 9,10-anthracenedimethanol is approximately one order of magnitude higher than with 9-anthracenemethanol.
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页码：464 / 467
页数：3
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