Kinetics and mechanism of photolysis of the iron(III) complex with tartaric acid

被引：0
|
作者：
Wu Feng
Deng Nansheng
E. M. Glebov
I. P. Pozdnyakov
V. P. Grivin
V. F. Plyusnin
N. M. Bazhin
机构：
[1] Wuhan University,Department of Environmental Science
[2] Wuhan,Institute of Chemical Kinetics and Combustion
[3] Siberian Branch of the Russian Academy of Sciences,undefined
[4] Novosibirsk State University,undefined
来源：
Russian Chemical Bulletin | 2007年 / 56卷
关键词：
photochemistry; Fe; complexes; carboxylic acids; aqueous solutions; UV spectra; laser flash photolysis;
D O I：
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中图分类号：
学科分类号：
摘要：
The formation of MV•+ radical cations was observed upon the laser flash photolysis of the iron(III) tartrate complex [FeIIITart]+ (1) in the presence of methyl viologen (MV2+). The rate constants of the reactions involving MV•+ were measured. The intramolecular electron trans-fer to form FeII and escape of the organic radical to the solvent bulk upon the photolysis of 1 were proposed.
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页码：900 / 903
页数：3
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