Kinetics and mechanism of photolysis of the iron(III) complex with tartaric acid

被引：0

作者：

Wu Feng

Deng Nansheng

E. M. Glebov

I. P. Pozdnyakov

V. P. Grivin

V. F. Plyusnin

N. M. Bazhin

机构：

[1] Wuhan University,Department of Environmental Science

[2] Wuhan,Institute of Chemical Kinetics and Combustion

[3] Siberian Branch of the Russian Academy of Sciences,undefined

[4] Novosibirsk State University,undefined

来源：

Russian Chemical Bulletin | 2007年 / 56卷

关键词：

photochemistry; Fe; complexes; carboxylic acids; aqueous solutions; UV spectra; laser flash photolysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The formation of MV•+ radical cations was observed upon the laser flash photolysis of the iron(III) tartrate complex [FeIIITart]+ (1) in the presence of methyl viologen (MV2+). The rate constants of the reactions involving MV•+ were measured. The intramolecular electron trans-fer to form FeII and escape of the organic radical to the solvent bulk upon the photolysis of 1 were proposed.

引用

页码：900 / 903

页数：3

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