Hydrothermal Synthesis, Crystal Structures and Photoluminescent Properties of Two New Co(II) Coordination Polymers Derived from Dicarboxylate and N-Donor Ligands

被引：0

作者：

Huanchao Liu

Feng Guo

机构：

[1] Dezhou University,Key Laboratory of Coordination Chemistry and Functional Materials in Universities of Shandong

来源：

Journal of Inorganic and Organometallic Polymers and Materials | 2012年 / 22卷

关键词：

Crystal structure; Hydrothermal reactions; Co(II); Luminescence; 1,3-Benzenedicarboxylate; 1,3-Benzenedicarboxylate; Nitroisophthalic acid; 1,4-Bis(imidazol-1-yl) benzene; 1,4-Bis(1-imidazol-yl)-2,5-dimethylbenzene;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Two new Co(II) coordination polymers with 5-position substituted 1,3-benzenedicarboxylate and N-donor auxiliary ligands, [Co(5-OH-ip)(L1)1.5(H2O)]n (1) and [Co(5-NO2-ip)(L2)1.5]n (2) (5-OH-ip = 5-hydroxyisophthalic acid, 5-NO2-ip = nitroisophthalic acid, L1 = 1,4-bis(imidazol-1-yl) benzene and L2 = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene), were synthesized by hydrothermal reactions. Complex 1 shows a 3-fold interpenetrating 3D framework with the topological symbol of (44·66). Complex 2 exhibits a 3D framework with the vertex symbol of (42·68). Furthermore the luminescent properties of 1 and 2 were investigated.

引用

页码：1391 / 1396

页数：5

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