Hydrothermal synthesis, crystal structures, and photoluminescent properties of two cadmium(II) coordination polymers derived from dicarboxylates and N-donor ligands

被引：9
|
作者：
Xu, Jiakun [1 ,2 ]
Sun, Xiaochun [3 ]
Ju, Caixia [1 ,4 ]
Yang, Lirong [5 ]
Bi, Caifeng [2 ]
Sun, Mi [1 ]
机构：
[1] Chinese Acad Fishery Sci, Yellow Sea Fisheries Res Inst, Qingdao, Peoples R China
[2] Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao, Peoples R China
[3] Natl Oceanog Ctr, Qingdao, Peoples R China
[4] Shanghai Ocean Univ, Coll Food Sci & Technol, Shanghai, Peoples R China
[5] Henan Univ, Coll Chem & Chem Engn, Kaifeng, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 15期
关键词：
Cd coordination polymers; Crystal structures; Luminescent properties; METAL-ORGANIC FRAMEWORKS; FLUORESCENT PROPERTIES; CONSTRUCTION; CARBOXYLATES; TOPOLOGIES; COMPLEXES; CD(II); ACID;
D O I：
10.1080/00958972.2013.813493
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two metal coordination polymers, [Cd(ipa)(L-1)(H2O)](n) (1) and [Cd(ipa)(L-2)](n) (2) [H(2)ipa=isophthalic acid, L-1=3,5-bis(imidazole-1-yl)pyridine and L-2=3,5-bis(benzoimidazo-1-ly)pyridine], have been synthesized and structurally characterized by IR, elemental analysis, XRD, and X-ray single-crystal diffraction. Complex 1 shows a twofold cds topological net and 2 features a 3-D pcu topological net. Luminescent properties of 1 and 2 were investigated in the solid state at room temperature.
引用
收藏
页码：2693 / 2701
页数：9
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