Thermal study of mononuclear Pd(II) complexes of the type [Pd(X)2(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)

被引：0
|
作者：
Francisco C. C. Arantes
Antonio C. Moro
Iolanda S. Klein
Cristiana da Silva
Adelino V. G. Netto
Antonio E. Mauro
Vânia M. Nogueira
机构：
[1] UNESP—Univ Estadual Paulista,Instituto de Química de Araraquara
来源：
Journal of Thermal Analysis and Calorimetry | 2011年 / 106卷
关键词：
Palladium (II) compounds; Thioureas; Pseudohalides; Thermal analysis;
D O I：
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学科分类号：
摘要：
The synthesis, spectroscopic characterization, and thermal analysis of the compounds [Pd(X)2(mtu)(PPh3)] (X = Cl− (1), SCN− (2); mtu = N-methylthiourea; PPh3 = triphenylphosphine) and [Pd(X)2(phtu)(PPh3)] (X = Cl− (3), SCN− (4); phtu = N-phenylthiourea) are described. The thermal decomposition of the compounds occurs in two, three, or four stages and the final decomposition products were identified as Pd0 by X-ray powder diffraction. The thermal stability order of the complexes is 4 > 3>2 > 1.
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页码：379 / 383
页数：4
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