SUBSTITUTION-REACTIONS OF [CUI(PPH3)3X] (X=CL, BR OR I) WITH N,N-DIMETHYL-N'-PHENYLTHIOUREA (DMPTH), N,N-DIBUTYL-N'-PHENYLTHIOUREA (DBPTH) AND 1,3-THIAZOLIDINE-2-THIONE (TZDTH)

被引：16

作者：

SINGH, R ^{[1
]}

DIKSHIT, SK ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA

来源：

POLYHEDRON | 1992年 / 11卷 / 16期

关键词：

D O I：

10.1016/S0277-5387(00)83167-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [Cu(PPh3)3X] with the titled ligands yield [GRAPHICS] The complexes have been characterized on the basis of analytical, IR, electronic (UV-vis), H-1, P-31 and C-13 NMR, conductivity and magnetic measurements. In all cases there is a distorted tetrahedral environment around copper(I), and the ligands (LH) bind through the thione sulphur atom to copper(I).

引用

页码：2099 / 2107

页数：9

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