Crystal structure of barium bis[N-(2-hydroxyethyl)iminodiacetato]cobaltate(III) hydrocarbonate dihydrate Ba(μ4-HCO3)[trans(N)-Co(heida)2]·2H2O

被引：0
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作者：
M. Zabel
A. L. Poznyak
V. I. Pavlovskii
机构：
[1] University of Regensburg,Institute of Inorganic Chemistry
[2] National Academy of Sciences,B. I. Stepanov Institute of Physics
来源：
Journal of Structural Chemistry | 2008年 / 49卷
关键词：
crystal structure; cobalt(III) complex; barium hydrocarbonate; N-(2-hydroxyethyl)iminodiacetate ion;
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学科分类号：
摘要：
Ba[Co(heida)2](HCO3)·2H2O crystals were grown (orthorhombic, a = 9.4491(5) Å, b = 10.9719(5) Å, c = 19.6077(9) Å, Z = 4, space group Pca21), and their structure was solved by X-ray diffraction. The Co atoms in the complex anion were coordinated by two N-(2-hydroxyethyl)iminodiacetate (heida) ligands via the N atom and two O atoms of each ligand. The Ba atoms and the complex anions form “honeycomb” layers linked via three O atoms. The “honeycombs” are additionally linked by their Ba atoms with the O atoms of the hydroxyethyl groups. The Ba atoms are aligned within a layer and linked via the bridging HCO3 hydrocarbonate groups. The c.n. of Ba atoms is 10 (one water molecule; five O atoms of the complex anions, one from each of the nearest neighbors; and four O atoms of the hydrocarbonate ions).
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页码：575 / 579
页数：4
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