Complex of Copper(II) with Ethylenediamine and Decyl Sulfate Ions. Formation in Water and Crystal Structure

被引：0
|
作者：
R. R. Amirov
I. A. Litvinov
A. T. Gubaidullin
U. V. Matyugicheva
机构：
[1] Kazan State Uiversity,Arbuzov Insitute of Organic and Physical Chemistry, Kazan Research Center
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of General Chemistry | 2003年 / 73卷
关键词：
Copper; Sulfate; Aqueous Solution; Crystal Structure; Ethylenediamine;
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学科分类号：
摘要：
Decyl sulfate ions form strong associates with ethylenediammonium cations and copper(II) ethylenediamine complexes. A solid compound of the composition copper(II):ethylenediamine:decyl sulfate ion = 1:2:2 was isolated from the aqueous solution; its crystal structure was studied to find that it comprises a regular combination of formula units of an inner-sphere complex bis(ethylenediamine)bis(decyl sulfato)copper(II) and a complex associate of two decyl sulfate ions with diaquabis(ethyenediamine)copper(II).
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页码：1860 / 1865
页数：5
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