Complex of Copper(II) with Ethylenediamine and Decyl Sulfate Ions. Formation in Water and Crystal Structure

被引：0
|
作者：
R. R. Amirov
I. A. Litvinov
A. T. Gubaidullin
U. V. Matyugicheva
机构：
[1] Kazan State Uiversity,Arbuzov Insitute of Organic and Physical Chemistry, Kazan Research Center
[2] Russian Academy of Sciences,undefined
来源：
Russian Journal of General Chemistry | 2003年 / 73卷
关键词：
Copper; Sulfate; Aqueous Solution; Crystal Structure; Ethylenediamine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Decyl sulfate ions form strong associates with ethylenediammonium cations and copper(II) ethylenediamine complexes. A solid compound of the composition copper(II):ethylenediamine:decyl sulfate ion = 1:2:2 was isolated from the aqueous solution; its crystal structure was studied to find that it comprises a regular combination of formula units of an inner-sphere complex bis(ethylenediamine)bis(decyl sulfato)copper(II) and a complex associate of two decyl sulfate ions with diaquabis(ethyenediamine)copper(II).
引用
收藏
页码：1860 / 1865
页数：5
相关论文
共 50 条
  • [1] Complex of copper(II) with ethylenediamine and decyl sulfate ions. Formation in water and crystal structure
    Amirov, RR
    Litvinov, IA
    Gubaidullin, AT
    Matyugicheva, UV
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2003, 73 (12) : 1860 - 1865
  • [2] KINETICS OF COPPER(II)-ETHYLENEDIAMINE COMPLEX FORMATION
    KIRSCHENBAUM, LJ
    JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (04): : 684 - +
  • [3] Crystal structure of the copper(II) complex with acetylacetone and ethylenediamine obtained by template synthesis
    A. M. Maharramov
    M. G. Tsintsadze
    R. A. Alieva
    F. N. Bahmanova
    F. O. Mamedova
    R. K. Askerov
    F. S. Alieva
    F. M. Chyragov
    Journal of Structural Chemistry, 2017, 58 : 828 - 830
  • [4] CRYSTAL STRUCTURE OF THE COPPER(II) COMPLEX WITH ACETYLACETONE AND ETHYLENEDIAMINE OBTAINED BY TEMPLATE SYNTHESIS
    Maharramov, A. M.
    Tsintsadze, M. G.
    Aliyeva, R. A.
    Bahmanova, F. N.
    Mamedova, F. O.
    Askerov, R. K.
    Alieva, F. S.
    Chyragov, F. M.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 58 (04) : 828 - 830
  • [5] Thermodynamics of copper(II)-ethylenediamine complex formation in water-methanol mixtures
    Repkin, GI
    Frolova, LN
    Nizkoshapkaya, OA
    Shormanov, VA
    ZHURNAL NEORGANICHESKOI KHIMII, 1997, 42 (08): : 1370 - 1372
  • [6] Tetrahydrated bis(ethylenediamine)copper(II) sulfate: Crystal structure, Raman spectrum and magnetic susceptibility
    Vakulka, Andrii
    Goreshnik, Evgeny
    Jagodic, Marko
    Jaglicic, Zvonko
    Trontelj, Zvonko
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1210
  • [7] SPECTROPHOTOMETRY OF COPPER(II) COMPLEX-FORMATION WITH ETHYLENEDIAMINE AND AMMONIA
    ERMAKOVA, VE
    SHAPNIK, MS
    ZHURNAL NEORGANICHESKOI KHIMII, 1976, 21 (08): : 2130 - 2133
  • [8] Synthesis and crystal structure of bi(ethylenediamine) copper tetracyanonickelate (II)
    Luo, JH
    Wu, MX
    Wang, YM
    Gao, DS
    Li, D
    Cheng, CZ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (03) : 187 - 190
  • [9] Synethesis and Crystal Structure of Bi(ethylenediamine)copper Tetracyanonickelate(II)
    LUO Jun Hua ②\ WU Mao Xiang\ WANG Yan Ming\ GAO Dong Shou Li Ding\ CHENG Chang Zhang (Fujian Insitute of Research on the Structure of Matter
    结构化学, 2000, (03) : 187 - 190
  • [10] STUDY OF COMPLEX-FORMATION OF COPPER(II) WITH ETHYLENEDIAMINE BY ESTERBERG METHOD
    SHAPNIK, MS
    PETROVA, TP
    ZHURNAL NEORGANICHESKOI KHIMII, 1980, 25 (05): : 1414 - 1418
12345