Towards chiral diamines as chiral catalytic precursors for the borane-mediated enantioselective reduction of prochiral ketones

被引：0
|
作者：
Deevi Basavaiah
Utpal Das
Suparna Roy
机构：
[1] University of Hyderabad,School of Chemistry
来源：
Journal of Chemical Sciences | 2009年 / 121卷
关键词：
(3; )-3-Anilinomethyl-1,2,3,4-tetrahydroisoquinoline; (2; )-2-anilinomethylpiperidine; (; )-phenylalanine; asymmetric reduction;
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中图分类号：
学科分类号：
摘要：
Two chiral diamines (3S)-3-anilinomethyl-1,2,3,4-tetrahydroisoquinoline (1) and (2R)-2-anilinomethylpiperidine (2) have been employed as chiral catalytic sources in the borane-mediated asymmetric reduction of prochiral ketones thus providing the resulting secondary alcohols in good enantiomeric purities (up to 81% ee).
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页码：1003 / 1010
页数：7
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