Thermal studies of cobalt(II), nickel(II) and copper(II) 3-substituted-4-salicylideneamino-5-mercapto-1,2,4-triazole complexes

被引：0

作者：

Prabhugouda B. Maravalli

Kalagouda B. Gudasi

Timmanagouda R. Goudar

机构：

[1] Karnatak University,Department of Chemistry

来源：

Transition Metal Chemistry | 2000年 / 25卷

关键词：

EtOH; Triazole; Triazole Ring; TCNE; Percentage Mass Loss;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Complexes of CoII, NiII and CuII with 3-substituted-4-salicylideneamino-5-mercapto-1,2,4-triazole have been prepared and characterized by elemental analysis, electronic, i.r., e.s.r. and t.g. studies. T.g. studies show that the complexes thermally degrade in two steps. Kinetic and thermodynamic parameters were computed from the thermal decomposition data. The activation energies of both the thermal degradation steps lie in the 0.24–42.67 kJ mol−1 range.

引用

页码：411 / 414

页数：3

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