A 119Sn Mössbauer Study of Tin(IV) Complexes of 2- and 4-Benzoylpyridine Thiosemicarbazone and 4-Benzoylpyridine Semicarbazone

被引：0
|
作者：
Anayive Pérez-Rebolledo
José D. Ardisson
Geraldo M. de Lima
Waldemar A. A. Macedo
Heloisa Beraldo
机构：
[1] Universidade Federal de Minas Gerais,Departamento de Química
[2] Centro de Desenvolvimento da Tecnologia Nuclear,Laboratório de Física Aplicada (LFA/CDTN)
来源：
Hyperfine Interactions | 2005年 / 163卷
关键词：
Sn Mössbauer; tin(IV) complexes; thiosemicarbazones; semicarbazones;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A 119Sn Mössbauer study was carried out of tin(IV) complexes with 2-benzoylpyridine thiosemicarbazone (H2Bz4DH) and its N(4)-methyl (H2Bz4M) and N(4)-phenyl (H2Bz4Ph) derivatives: [Sn(2Bz4DH)Cl3] (1), [Sn(2Bz4DH)PhCl2] (2), [Sn(2Bz4M)Cl3] (3), [H22Bz4M]2[Ph2SnCl4] (4), [Sn(2Bz4Ph)PhCl2] (5), [Sn(2Bz4Ph)Ph2Cl] (6), in which H2Bz4R stands for the neutral ligand and 2Bz4R stands for the anionic thiosemicarbazone. In addition, 119Sn Mössbauer studies of the tin(IV) complexes [Sn(H4Bz4DH)2Cl4H2O] (7), [Sn(H4BzPS)2Cl4H2O] (8) with 4-benzoylpyridine thiosemicarbazone (H4Bz4DH) and the correspondent semicarbazone (H4BzPS) were performed. The isomer shifts decrease upon coordination due to the variation in the percentage of s character as tin changes from approximately sp3 hybridization in the tin salts to sp3d2 in the octahedral or sp3d3 in the heptahedral complexes. The Mössbauer parameters of compound (4) showed the existence of two tin(IV) sites, which have been attributed to the presence of the cis and trans isomers.
引用
收藏
页码：89 / 94
页数：5
相关论文
共 50 条
  • [21] Tin(IV) complexes of 2-benzoylpyridine N(4)-phenyl-thiosemicarbazone:: spectral characterization, structural studies and antifungal activity
    Rebolledo, AP
    de Lima, GM
    Gambi, LN
    Speziali, NL
    Maia, DF
    Pinheiro, CB
    Ardisson, JD
    Cortés, ME
    Beraldo, H
    APPLIED ORGANOMETALLIC CHEMISTRY, 2003, 17 (12) : 945 - 951
  • [22] STRUCTURES OF TETRAKIS(4-BENZOYLPYRIDINE)BIS(ISOTHIOCYANATO)COBALT(II) (1) AND BIS(4-ACETYLPYRIDINE)DIAQUABIS(ISOTHIOCYANATO)COBALT(II) (2)
    DREW, MGB
    GRAY, NI
    CABRAL, MF
    CABRAL, JD
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (OCT) : 1434 - 1437
  • [23] Molecular, Supramolecular Structures Combined with Hirshfeld and DFT Studies of Centrosymmetric M(II)-azido {M=Ni(II), Fe(II) or Zn(II)} Complexes of 4-Benzoylpyridine
    Abu-Youssef, Morsy A. M.
    Langer, Vratislav
    Barakat, Assem
    Haukka, Matti
    Soliman, Saied M.
    SYMMETRY-BASEL, 2021, 13 (11):
  • [24] 119Sn Mössbauer, NMR (1H, 13C and 119Sn) and infrared study of tetracoordinated tin(IV) complexes with 4-[((E)-1-{2-hydroxy-5-[(E)-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoates
    Tushar S. Basu Baul
    Pradip Das
    Eleonora Rivarola
    Hyperfine Interactions, 2009, 194 : 391 - 400
  • [25] Study of tin amalgam mirrors by 119Sn Mössbauer spectroscopy and other analytical methods
    A. Lerf
    F. E. Wagner
    L. K. Herrera
    A. Justo
    A. Mu noz-Páez
    J. L. Pérez-Rodríguez
    Hyperfine Interactions, 2016, 237
  • [26] Thermodynamic studies of some complexes of 2-benzoylpyridine 4-phenyl-3-thiosemicarbazone
    Atalay, T
    Akgemci, EG
    TURKISH JOURNAL OF CHEMISTRY, 1998, 22 (02): : 123 - 127
  • [27] 1:4 Complexes of cobalt(II) azide with pyridine derivative ligands. X-ray crystal structure of trans-diazidotetrakis(4-benzoylpyridine) cobalt(II)
    Goher, Mohamed A. S.
    Mautner, Franz A.
    Transition Metal Chemistry, 24 (06): : 693 - 696
  • [28] 1:4 complexes of cobalt(II) azide with pyridine derivative ligands.: X-ray crystal structure of trans-diazidotetrakis(4-benzoylpyridine) cobalt(II)
    Goher, MAS
    Mautner, FA
    TRANSITION METAL CHEMISTRY, 1999, 24 (06) : 693 - 696
  • [29] 1:4 Complexes of cobalt(II) azide with pyridine derivative ligands. X-ray crystal structure of trans-diazidotetrakis(4-benzoylpyridine) cobalt(II)
    Mohamed A. S. Goher
    Franz A. Mautner
    Transition Metal Chemistry, 1999, 24 : 693 - 696
  • [30] 119Sn Mössbauer study of nickel–tin anodes for rechargeable lithium-ion batteries
    S. Naille
    P. E. Lippens
    F. Morato
    J. Olivier-Fourcade
    Hyperfine Interactions, 2006, 167 : 785 - 790
12345