Ethylene to Propylene Conversion over Ni-W/ZSM-5 Catalyst

被引:0
|
作者
Ehsan Kianfar
机构
[1] Islamic Azad University,Department of Chemical Engineering, Arak Branch
[2] Islamic Azad University,Young Researchers and Elite Club, Gachsaran Branch
来源
关键词
ethylene; propylene; fixed-bed reactor; catalyst ZSM-5; modified catalyst; Ni-W/ZSM-5;
D O I
暂无
中图分类号
学科分类号
摘要
A ZSM-5 base is used to produce light olefins in the process of converting ethylene to propylene, as well as Ni-W/ZSM-5 to improve the catalyst. After loading the Ni-W/ZSM-5 0.5,1,2 wt % by inoculation, the modified catalyst was investigated for accurate determination of the specification by SEM, BET, FTIR analyzes. The activity of this catalyst was evaluated in the process of ethylene to propylene conversion in a constant reactor under operational conditions (temperature 400°C, pressure 1 atm, and feed flow rate of 0.5 cm3/min of pure ethylene), which also shows the results of tests of catalyst activity evaluation. The selectivity of ethylene and propylene over the modified catalyst will increase as the temperature rises and the maximum selectivity will be achieved at 400°C. The catalyst with 0.5 wt % Ni/ZSM-5 has the highest conversion rate and better selectivity than that with other percentages, also the catalyst with 2 wt % Ni-W/ZSM-5 has the highest conversion rate and better selectivity than other percentages.
引用
收藏
页码:1094 / 1101
页数:7
相关论文
共 50 条
  • [21] Removal of NO by Selective Catalytic Reduction with Ethylene over Catalyst Cu/ZSM-5
    Hu, Jiangjun
    Ma, Qian
    Ouyang, Ling
    Chen, Xi
    Gan, Fuxing
    FRONTIERS OF GREEN BUILDING, MATERIALS AND CIVIL ENGINEERING, PTS 1-8, 2011, 71-78 : 2806 - 2813
  • [22] CONVERSION OF METHANOL TO ETHYLENE OVER ZSM-5 ZEOLITE IN THE PRESENCE OF DEUTERATED WATER
    MOLE, T
    WHITESIDE, JA
    JOURNAL OF CATALYSIS, 1982, 75 (02) : 284 - 290
  • [23] Deactivation pathways during methanol to propylene (MTP) conversion over ZSM-5 catalysts
    Mueller, Sebastian
    Liu, Yue
    Sanchez-Sanchez, Maricruz
    Lercher, Johannes August
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [24] Size Effect of ZSM-5 on Diffusion and Catalytic Performance in Syngas Conversion to Aromatics over MnCrO x -ZSM-5 Catalyst
    Zhang, Shuchi
    Miao, Dengyun
    Ding, Yi
    Wang, Haodi
    Peng, Tao
    Jiao, Feng
    Pan, Xiulian
    JOURNAL OF PHYSICAL CHEMISTRY C, 2025, 129 (03): : 1582 - 1589
  • [26] The Transformation of Light Paraffins to LPG and Aromatics Over a Ni/ZSM-5 Catalyst
    Viswanadham, N.
    Saxena, S. K.
    Kumar, M.
    PETROLEUM SCIENCE AND TECHNOLOGY, 2011, 29 (04) : 393 - 400
  • [27] THE CONVERSION OF ETHANOL TO HYDROCARBONS OVER ZSM-5
    SAHA, SK
    SIVASANKER, S
    INDIAN JOURNAL OF TECHNOLOGY, 1992, 30 (02): : 71 - 76
  • [28] Phosphorus-modified ZSM-5 for conversion of ethanol to propylene
    Song, Zhaoxia
    Takahashi, Atsushi
    Nakamura, Isao
    Fujitani, Tadahiro
    APPLIED CATALYSIS A-GENERAL, 2010, 384 (1-2) : 201 - 205
  • [29] Effect of acidity of ZSM-5 zeolite on conversion of ethanol to propylene
    Furumoto, Yoshiyasu
    Harada, Yasumitsu
    Tsunoji, Nao
    Takahashi, Atsushi
    Fujitani, Tadahiro
    Ide, Yusuke
    Sadakane, Masahiro
    Sano, Tsuneji
    APPLIED CATALYSIS A-GENERAL, 2011, 399 (1-2) : 262 - 267
  • [30] Catalytic cracking of light diesel over Au/ZSM-5 catalyst for increasing propylene production
    Qi, Caixia
    Wang, Yunxia
    Ding, Xiaotao
    Su, Huijuan
    CHINESE JOURNAL OF CATALYSIS, 2016, 37 (10) : 1747 - 1755