Synthesis and photoluminescent properties of new cationic carbazole-containing luminophores

被引:0
|
作者
A. Baran
A. Plotniece
A. Sobolev
B. Vigante
M. Gosteva
V. Olkhovik
机构
[1] Latvian Institute of Organic Synthesis,Institute of the Chemistry of Novel Materials
[2] National Academy of Sciences of Belarus,undefined
来源
关键词
-alkylpyridinium derivatives; carbazole derivatives; luminescent cell probes; stilbenoids; photoluminescence;
D O I
暂无
中图分类号
学科分类号
摘要
The synthesis of a series of new π-conjugated amphiphilic derivatives of carbazole of the "stilbene" type, substituted with N-alkylpyridinium groups at positions 2 and 7, is described. Due to the presence of polar cationic groups and nonpolar alkyl substituents, the obtained compounds are potentially capable of acting as agents for the transportation of genetic material inside a cell, and the extended and effective conjugation chain leads to the appearance of intense photoluminescence both in solutions and in biological media, making it possible to use them as cell probes. The absorption maxima of the compounds are in the region of 422-450 nm, while the luminescence maxima are in the yellow-green region at 575-617 nm.
引用
收藏
页码:287 / 295
页数:8
相关论文
共 50 条
  • [21] Preparation and properties of two new soluble carbazole-containing functional polyacetylenes
    Zhu, Wei Ju
    Wu, Zhen Yu
    Song, Ji Ming
    Li, Cun
    CHINESE CHEMICAL LETTERS, 2011, 22 (09) : 1017 - 1020
  • [22] Synthesis and photoluminescence of carbazole-containing polyacetylenes.
    Lee, PPS
    Cheuk, KKL
    Dong, YP
    Chau, FSW
    Tang, BZ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U411 - U411
  • [23] SOME PHOTOPHYSICAL PROPERTIES OF 5 NEW CARBAZOLE-CONTAINING METHACRYLATE POLYMERS
    KEYANPOURRAD, M
    LEDWITH, A
    HALLAM, A
    NORTH, AM
    BRETON, M
    HOYLE, C
    GUILLET, JE
    MACROMOLECULES, 1978, 11 (06) : 1114 - 1118
  • [24] Synthesis and Characterization of New Photoluminescent Oxadiazole/Carbazole Containing Polymers
    Concilio, Simona
    Bugatti, Valeria
    Iannelli, Pio
    Piotto, Stefano P.
    5TH INTERNATIONAL CONFERENCE ON TIMES OF POLYMERS TOP AND COMPOSITES, 2010, 1255 : 178 - +
  • [25] New carbazole-containing chalcones and pyrimidines based thereon: Synthesis and electrochemical study
    R. V. Syutkin
    G. G. Abashev
    E. V. Shklyaeva
    P. G. Kudryavtsev
    Russian Journal of Organic Chemistry, 2011, 47 : 530 - 536
  • [26] Synthesis and reactivity of carbazole-containing hypervalent iodine(Ⅲ) reagents
    Tianlei Lan
    Haijuan Qin
    Wenting Chen
    Wei Liu
    Chao Chen
    Chinese Chemical Letters, 2020, 31 (02) : 357 - 360
  • [27] Synthesis and characterization of novel carbazole-containing soluble polyimides
    Department of Chemistry, Queen's University, Kingston, Ont. K7L 3N6, Canada
    Macromolecules, 10 (3171-3177):
  • [28] Synthesis, characterization and photoelectric properties of a novel carbazole-containing Re(I) complex
    Sun, M
    Xin, H
    Zhang, YA
    Wang, KZ
    Jin, LP
    Huang, CH
    ACTA CHIMICA SINICA, 2003, 61 (08) : 1323 - 1325
  • [29] Carbazole-containing lightemitting polymers:Properties of excited states
    LIN Hongzhen
    ChineseScienceBulletin, 2003, (07) : 637 - 642
  • [30] Synthesis and characterization of novel carbazole-containing soluble polyimides
    Chen, JP
    Natansohn, A
    MACROMOLECULES, 1999, 32 (10) : 3171 - 3177