Synthesis and Characterization of Ferrocene-Containing Hyperbranched Poly(aroylarylene)s

被引:0
|
作者
Hongchen Dong
Anjun Qin
Cathy K. W. Jim
Jacky W. Y. Lam
Matthias Häuβler
Ben Zhong Tang
机构
[1] The Hong Kong University of Science & Technology,Department of Chemistry
[2] Zhejiang University,Department of Polymer Science & Engineering
关键词
Cyclotrimerization; Ferrocene; Hyperbranched polymer;
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摘要
Ferrocene-containing hyperbranched poly(aroylarylene)s are prepared in satisfactory yields by one-pot copolycyclotrimerization of bis(aroylacetylene)s with a ferrocene-containing monoyne. The ferrocene content of the polymers can be varied by changing the monomer feed ratio, and copolymers with up to 41 mol% of ferrocene moiety can be readily prepared. All the polymers are thermally stable, losing little of their weights when heated to 340 °C.
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页码:201 / 205
页数:4
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