Crystal and Molecular Structure of {1,2-Bis[2-(o-hydroxyphenoxy)ethoxy]ethane}bis(isothiocyanato)calcium

被引：0
|
作者：
A. N. Chekhlov
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Journal of General Chemistry | 2004年 / 74卷
关键词：
Oxygen; Hydrogen; Nitrogen; Calcium; Hydrogen Bond;
D O I：
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中图分类号：
学科分类号：
摘要：
The crystal, molecular structure of {1'2-bis[2-(o-hydroxyphenoxy)ethoxy]ethane}bis(iso-thiocyanato)calcium was studied by single crystal X-ray diffraction. The compound is a host-guest complex.In the molecule of this complex, the podand is “wrapped” around the Ca2+ cation (CN 8), which is coordi- nated with all the six oxygen atoms of the podand and with two nitrogen atoms of two SCN- ligands. The geometric parameters and crystal packing of the complex were determined. The molecules in the crystal are linked by O-H···S hydrogen bonds to form three-dimensional layers.
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页码：721 / 724
页数：3
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