Atom Transfer Radical Polymerisation with an Immobilised [RuCl2(p-cymene)]2 Dimer

被引:0
|
作者
T. Opstal
K. Melis
F. Verpoort
机构
[1] Ghent University,Department of Inorganic and Physical Chemistry
来源
Catalysis Letters | 2001年 / 74卷
关键词
MCM-41 materials; heterogeneous catalysis; atom transfer radical polymerisation;
D O I
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中图分类号
学科分类号
摘要
[RuCl2(p-cymene)]2 has been immobilized on silica and mesoporous MCM-41 and used as a catalyst for the atom transfer radical polymerisation (ATRP) of styrene, (methyl)methacrylate and acrylonitrile. The heterogeneous catalyst has a comparable activity as the homogeneous analogues and showed no significant loss of catalytic activity when reused.
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页码:155 / 159
页数:4
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