A Batch Chemiluminescence Determination of Enoxacin Using a Tris-(1,10-phenanthroline)ruthenium(II)–Cerium(IV) System

被引：0
|
作者：
Mohammad Mainul Karim
Sang Hak Lee
Hyun Sook Lee
Zun Ung Bae
Kyoung Hye Choi
机构：
[1] Kyungpook National University,Department of Chemistry
[2] Kyungpook National University,Department of Sensor and Display Engineering
来源：
Journal of Fluorescence | 2006年 / 16卷
关键词：
Batch chemiluminescence; Enoxacin; Ruthenium; Cerium; Serum;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A batch type chemiluminescence (CL) determination of enoxacin is described. In this work, it was observed that enoxacin could enhance the chemiluminescence (CL) emission Ru(phen)32+–Ce(IV) system and this enhancement effect was dependent on the concentration of enoxacin, based on which, CL system was established for the determination of enoxacin. Under the optimum experimental conditions, the linear range and detection limit are 0.6406–64.06 μg/ml and 0.0210 μg/ml, respectively. The R.S.D. is 1.75%. (n=10). The proposed method has been applied to detect the content of enoxacin in pharmaceutical formulation and human serum with satisfactory results. The possible mechanism of the CL reaction was discussed.
引用
收藏
页码：535 / 540
页数：5
相关论文
共 50 条
  • [21] High-Performance Liquid Chromatographic Determination of Oxalic Acid in Tea Using Tris(1,10-phenanthroline)-ruthenium(II) Chemiluminescence
    Department of Chemistry, Wuhan University, Wuhan 430072, China
    [J]. Anal. Sci., 5 (971-973):
  • [22] High-performance liquid chromatographic determination of oxalic acid in tea using tris(1,10-phenanthroline)-ruthenium(II) chemiluminescence
    Wu, FW
    He, Z
    Luo, QY
    Zeng, Y
    [J]. ANALYTICAL SCIENCES, 1998, 14 (05) : 971 - 973
  • [23] High-Performance Liquid Chromatographic Determination of Oxalic Acid in Tea Using Tris(1,10-phenanthroline)-ruthenium(II) Chemiluminescence
    Fengwu Wu
    Zhike He
    Qingyao Luo
    Yun’e Zeng
    [J]. Analytical Sciences, 1998, 14 : 971 - 973
  • [24] Tris (acetylacetonato)(1,10-phenanthroline)-cerium(III) and tris(acetylacetonato)(1,10-phenanthroline)praseodymium(III)
    Christidis, PC
    Tossidis, IA
    Paschalidis, DG
    Tzavellas, LC
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1233 - 1236
  • [25] ROTATORY STRENGTHS OF THE ELECTRON-TRANSFER TRANSITIONS OF THE TRIS-(1,10-PHENANTHROLINE)RUTHENIUM(II) ION
    KRAL, M
    [J]. THEORETICA CHIMICA ACTA, 1979, 50 (04): : 355 - 357
  • [26] KINETICS AND MECHANISM OF OXIDATION OF TRIS-(1,10-PHENANTHROLINE)IRON(II) BY CHLORINE AND BROMINE AND OF THE REDUCTION OF "TRIS-(1,10-PHENANTHROLINE)IRON(III) BY IODIDE-IONS
    IGE, J
    OJO, JF
    OLUBUYIDE, O
    [J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1979, 57 (15): : 2065 - 2070
  • [27] Determination of prednisone acetate at trace level by flow injection analysis with tris(1,10-phenanthroline) ruthenium(II) chemiluminescence detection
    Gong, Pixue
    Liu, Weihua
    Liu, Wenwen
    Du, Kang
    Liu, Kang
    Cao, Wei
    [J]. APPLICATION OF CHEMICAL ENGINEERING, PTS 1-3, 2011, 236-238 : 2729 - +
  • [28] Determination of zinc(II) using the micellar enhanced chemiluminescence of 1,10-phenanthroline
    Watanabe, K
    Miyamoto, H
    Itagaki, M
    [J]. BUNSEKI KAGAKU, 1999, 48 (07) : 705 - 710
  • [29] FLUORIMETRIC DETERMINATION OF RUTHENIUM USING 1,10-PHENANTHROLINE
    SHCHERBO.DP
    IVANKOVA, AI
    GLADYSHE.GP
    [J]. INDUSTRIAL LABORATORY, 1972, 37 (11): : 1665 - &
  • [30] LUMINESCENCE DETERMINATION OF RUTHENIUM USING 1,10-PHENANTHROLINE
    GOLOVANOV, SP
    GOLOVINA, AP
    RUNOV, VK
    SADVAKASOVA, SK
    CHEMLEVA, TA
    KHVOSTOVA, VP
    [J]. JOURNAL OF ANALYTICAL CHEMISTRY OF THE USSR, 1984, 39 (09): : 1323 - 1328
12345