Synthesis, structure, and properties of nickel complexes with nitrilotris(methylenephosphonic acid) [Ni(H2O)3N(CH2PO3H)3] and Na4[Ni(H2O)N(CH2PO3)3] ∙ 11H2O

被引：0
|
作者：
N. V. Somov
F. F. Chausov
R. M. Zakirova
I. V. Fedotova
机构：
[1] Lobachevsky Nizhny Novgorod State University,Physico
[2] Russian Academy of Sciences,Technical Institute, Ural Branch
[3] Udmurt State University,undefined
来源：
Crystallography Reports | 2016年 / 61卷
关键词：
Crystallography Report; Coordination Polyhedron; Nickel Complex; Distorted Octahedral Coordination; Structure Refinement Statistic;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Nitrilotris(methylenephosphonato)triaquanickel and tetrasodium nitrilotris(methylenephosphonato) aquanickelate undecahydrate were synthesized and characterized. The crystal of [Ni(H2O)3N(CH2PO3H)3] is composed of linear coordination polymers and belongs to sp. gr. P21/c, Z = 4, a = 9.17120(10) Å, b = 16.05700(10) Å, c = 9.70890(10) Å, β = 115.830(2)°. The Ni atom is in an octahedral coordination formed by two oxygen atoms of one phosphonate ligand, one oxygen atom of another ligand molecule, and three water molecules in a meridional configuration. The crystal of Na4[Ni(H2O)N(CH2PO3)3] ∙ 11H2O has an island dimeric chelate structure and belongs to sp. gr. С2/c, Z = 8, a = 18.7152(2) Å, b = 12.05510(10) Å, c = 21.1266(2) Å, β = 104.4960(10)°. The Ni atom has a slightly distorted octahedral coordination involving one nitrogen atom and closes three five-membered N–C–P–O–Ni rings sharing the Ni–N bond.
引用
收藏
页码：216 / 224
页数：8
相关论文
共 50 条
  • [11] Nitrilotris(methylenephosphonic) Complexes of Lanthanides [Na(H2O)x]2[LnIIINa6H(H2O)10{N(CH2PO3)3}2] • nH2O (LnIII = Pr, Nd)
    Somov, N. V.
    Chausov, F. F.
    Lomova, N. V.
    Zakirova, R. M.
    Fedotova, I. V.
    Petrov, V. G.
    Shumilova, M. A.
    Zhirov, D. K.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2019, 45 (01) : 47 - 55
  • [12] Synthesis, structure, and properties of the stabilized coordination chrome(II) complex with nitrilotris(methylenephosphonic) acid [CrII(H2O)3-μ-NH(CH2PO3H)3]
    Somov, N. V.
    Chausov, F. F.
    Zakirova, R. M.
    Fedotova, I. V.
    Shumilova, M. A.
    Aleksandrov, V. A.
    Petrov, V. G.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2015, 41 (10) : 688 - 694
  • [13] Synthesis, structure, and properties of the stabilized coordination chrome(II) complex with nitrilotris(methylenephosphonic) acid [CrII(H2O)3-μ-NH(CH2PO3H)3]
    N. V. Somov
    F. F. Chausov
    R. M. Zakirova
    I. V. Fedotova
    M. A. Shumilova
    V. A. Aleksandrov
    V. G. Petrov
    Russian Journal of Coordination Chemistry, 2015, 41 : 688 - 694
  • [14] Structure of complexes of nitrilo tris methylene phosphonic acid with copper, [CuN(CH2PO3)3(H2O)3] and Na4[CuN(CH2PO3)3]2 · 19H2O, as bactericides and inhibitors of scaling and corrosion
    N. V. Somov
    F. F. Chausov
    Crystallography Reports, 2015, 60 : 210 - 216
  • [15] Structure of Complexes of Nitrilo Tris Methylene Phosphonic Acid with Copper, [CuN(CH2PO3)3(H2O)3] and Na4[CuN(CH2PO3)3]2 • 19H2O, As Bactericides and Inhibitors of Scaling and Corrosion
    Somov, N. V.
    Chausov, F. F.
    CRYSTALLOGRAPHY REPORTS, 2015, 60 (02) : 210 - 216
  • [16] Aqua{pentahydrogennitrilotris(methylenephosphonato)}lithium hydrate [Li(H2O){N(CH2PO3)3H5}] • H2O: Synthesis and structure
    Somov, N. V.
    Chausov, F. F.
    Zakirova, R. M.
    CRYSTALLOGRAPHY REPORTS, 2016, 61 (03) : 395 - 400
  • [17] Aqua{pentahydrogennitrilotris(methylenephosphonato)}lithium hydrate [Li(H2O){N(CH2PO3)3H5}] • H2O: Synthesis and structure
    N. V. Somov
    F. F. Chausov
    R. M. Zakirova
    Crystallography Reports, 2016, 61 : 395 - 400
  • [18] Synthesis and structure of bis-hexaaquasodium bis-nitrilotris(methylenephosphonato)decaaquamonohydrohexasodiumlanthanate trihydrate [Na(H2O)6]2[LaNa6H(H2O)10{N(CH2PO3)3}2] · 3H2O
    N. V. Somov
    F. F. Chausov
    R. M. Zakirova
    V. G. Petrov
    M. A. Shumilova
    V. A. Aleksandrov
    Russian Journal of Coordination Chemistry, 2017, 43 : 373 - 379
  • [19] Synthesis and structure of bis-hexaaquasodium bis-nitrilotris(methylenephosphonato)decaaquamonohydrohexasodiumlanthanate trihydrate [Na(H2O)6]2[LaNa6H(H2O)10{N(CH2PO3)3}2] • 3H2O
    Somov, N. V.
    Chausov, F. F.
    Zakirova, R. M.
    Petrov, V. G.
    Shumilova, M. A.
    Aleksandrov, V. A.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (06) : 373 - 379
  • [20] Aquanitrilotris(methylenephosphonato)bis(dimercury(I)) Hydrate, [(Hg2)2(H2O) N(CH2PO3)3H2]•H2O: Synthesis, Structure, and Properties
    Somov, N. V.
    Chausov, F. F.
    Zakirova, R. M.
    Shumilova, M. A.
    Aleksandrov, V. A.
    Petrov, V. G.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2016, 42 (01) : 37 - 43
12345