2D CdI2 topological layer architecture constructed by Zn(II) and flexible tricarboxylate ligand

被引：0
|
作者：
S. Sun
G. X. Zhang
J. Q. Gao
Z. B. Han
机构：
[1] Liaoning University,College of Chemistry
来源：
Russian Journal of Coordination Chemistry | 2012年 / 38卷
关键词：
Coordination Polymer; Coordination Mode; Solvothermal Condition; Paddle Wheel; Alkox;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new coordination polymer, [(CH3)2NH2][Zn(Tci)] · 2.5H2O (I) (H3Tci = tris(2-carboxyethyl)isocyanurate), has been synthesized under solvothermal conditions. X-ray diffraction analysis reveals that I features a 2D anionic layer structure constructed by Zn(II) paddle-wheel building blocks and Tci linkers. The Zn(II) paddle-wheel can be viewed as a node, and the network of I can be simplicated as CdI2 net. Hydrogen bond interactions link the adjacent 2D layers to form a 3D supramolecular framework.
引用
收藏
页码：315 / 318
页数：3
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