Kinetics of the Reaction of Ozone with tert-Butanol

被引：0
|
作者：
N. Ya. Shafikov
A. A. Gusmanov
Yu. S. Zimin
V. D. Komissarov
机构：
[1] Bashkortostan State University,
[2] Ufa,undefined
来源：
Kinetics and Catalysis | 2002年 / 43卷
关键词：
Oxidation; Physical Chemistry; Hydrated; Ozone; Kinetic Parameter;
D O I：
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中图分类号：
学科分类号：
摘要：
The kinetics of tert-butanol (ROH) oxidation by ozone in CCl4 and H2O solutions at 295 K is studied by spectrophotometry under batch conditions. The rate-limiting step of the process in both solvents is the reaction of ozone with the monomeric form of ROH. In H2O, the hydrated molecules of ROH and ozone react with each other. In CCl4, the association of ROH molecules, which changes the kinetics and mechanism of the process, should be taken into account. The reaction kinetic parameters and the dimerization constant of ROH in CCl4 are determined.
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页码：799 / 801
页数：2
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