Thermal decomposition of PTFE in the presence of silicon, calcium silicide, ferrosilicon and iron

被引：0
|
作者：
A. Książczak
Henryka Boniuk
S. Cudziło
机构：
[1] Warsaw University of Technology,Department of Chemistry
[2] Military University of Technology,Institute of Chemistry
来源：
Journal of Thermal Analysis and Calorimetry | 2003年 / 74卷
关键词：
silicon-PTFE mixtures; thermal decomposition; TG/DTA; kinetics;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Simultaneous TG/DTA has been used to study the thermal decomposition of binary compositions containing polytetrafluoroethene (PTFE) with silicon (Si), calcium silicide (CaSi2), ferrosilicon (FeSi) or iron (Fe) powders. In nitrogen and under dynamic heating program the thermal decomposition of Si/PTFE and CaSi2/PTFE is an exothermic process. The other two compositions decompose endothermically. In each case the decomposition reactions show first-order kinetics but only iron does not change considerably the kinetics of PTFE depolymerization. The constants of the decomposition rate at 850 K for silicon containing reducers are about four times higher than those of PTFE and Fe/PTFE.
引用
下载
收藏
页码：569 / 574
页数：5
相关论文
共 50 条
  • [21] Microdisperse Iron Silicide Structures Produced by Implantation of Iron Ions in Silicon
    M. Dobler
    H. Reuther
    W. Möller
    Hyperfine Interactions, 1998, 112 : 185 - 188
  • [22] Brief observe on iron silicide growth on amorphous silicon
    Gouralnik, A. S.
    Lin, Ko-Wei
    Dotsenko, S. A.
    Galkin, N. G.
    Plotnikov, V. S.
    Pustovalov, E. V.
    Cherednichenko, A. I.
    Vavanova, S. V.
    Shevlyagin, A. V.
    Gutakovski, A. K.
    Neklyudova, M. A.
    PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 10, NO 12, 2013, 10 (12): : 1742 - 1745
  • [23] DEEP LEVELS IN SILICON AFTER IRON SILICIDE FORMATION
    ERLESAND, U
    OSTLING, M
    SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1995, 10 (12) : 1645 - 1651
  • [24] VOLUMETRIC DETERMINATION OF ALUMINUM IN PRESENCE OF IRON, TITANIUM, CALCIUM, SILICON, AND OTHER IMPURITIES
    WATTS, HL
    ANALYTICAL CHEMISTRY, 1958, 30 (05) : 967 - 970
  • [25] THERMAL-DECOMPOSITION OF CACO3 IN THE PRESENCE OF CALCIUM-FLUORIDE
    GORZKOWSKA, I
    MACIEJEWSKI, M
    RUDNICKI, R
    JOURNAL OF THERMAL ANALYSIS, 1988, 33 (03): : 983 - 990
  • [26] Formation of CaO from thermal decomposition of calcium carbonate in the presence of carboxylic acids
    N. B. Singh
    N. P. Singh
    Journal of Thermal Analysis and Calorimetry, 2007, 89 : 159 - 162
  • [27] Formation of CaO from thermal decomposition of calcium carbonate in the presence of carboxylic acids
    Singh, N. B.
    Singh, N. P.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2007, 89 (01) : 159 - 162
  • [28] CONTRIBUTION TO X-RAY SPECTROMETRIC ANALYSIS OF FERROSILICON AND CALCIUM-SILICON
    WAGNER, F
    ARCHIV FUR DAS EISENHUTTENWESEN, 1968, 39 (10): : 759 - &
  • [29] THERMAL-DECOMPOSITION OF SURFACTANTS IN PTFE-DISPERSIONS
    HOLZE, R
    RIGA, AT
    YEAGER, EB
    JOURNAL OF MATERIALS SCIENCE LETTERS, 1986, 5 (08) : 819 - 822
  • [30] Slag formation in silicon and ferrosilicon production using quartz, limestone and iron source
    Sarina Bao
    Eli Ringdalen
    International Journal of Minerals,Metallurgy and Materials, 2025, (04) : 859 - 868
12345