Structure of the Planar Acetate-Bridged Binuclear Copper(II) Complex Based on 1,3-Bis(3-Formyl-5-tert-Butylsalicylidenimino)propanol-2

被引：0
|
作者：
S. I. Levchenkov
L. D. Popov
Yu. P. Tupolova
A. N. Morozov
E. A. Raspopova
Z. A. Starikova
I. N. Shcherbakov
机构：
[1] Russian Academy of Sciences,Southern Scientific Center
[2] Southern Federal University,Nesmeyanov Institute of Organoelement Compounds
[3] Russian Academy of Sciences,undefined
来源：
Russian Journal of Coordination Chemistry | 2017年 / 43卷
关键词：
binuclear copper(II) complexes; magnetochemistry; exchange interaction; X-ray diffraction analysis;
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摘要：
The X-ray diffraction and magnetochemical studies of the acetate-bridged binuclear copper(II) complex with 1,3-bis(3-formyl-5-tert-butylsalicylidenimino)propanol-2 with a nearly planar structure of the exchange fragment are carried out (СIF file CCDC 940849). The assumption that the magnetic exchange in the complexes with the anticomplementary carboxylate exogenic bridges 1,3-O,O' is determined only by the structural factors and the bridging coordination of the solvent molecule changes the type of the exchange interaction between the copper(II) ions is proved to be true.
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页码：630 / 634
页数：4
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