Oxidation ofn-butane and propene on exhydrotalcite Mg, Al, Fe mixed oxides

被引:0
|
作者
M. J. Holgado
M. S. San Román
V. Rives
机构
[1] Universidad de Salamanca,Departmento de Química Inorgánica
来源
Reaction Kinetics and Catalysis Letters | 1998年 / 65卷
关键词
Oxidative dehydrogenation; ODH; mixed oxides; LDH;
D O I
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学科分类号
摘要
Oxidative dehydrogenation ofn-butane and propene has been studied on six Mg−Al−Fe oxide catalysts prepared by thermal decomposition of layered double hydroxides with a hydrotalcite-like structure, possessing Mg2+ and Al3+ ions in the brucite-like layers, and hexacyanoferrate in the interlayers. In all cases, CO2 and H2O are formed, together with minor amounts of ethylene and methane. On the solids prepared from hexacyanoferrate(II), formation of benzene is also observed.
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页码:53 / 58
页数:5
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