Oxidation ofn-butane and propene on exhydrotalcite Mg, Al, Fe mixed oxides

被引:0
|
作者
M. J. Holgado
M. S. San Román
V. Rives
机构
[1] Universidad de Salamanca,Departmento de Química Inorgánica
来源
Reaction Kinetics and Catalysis Letters | 1998年 / 65卷
关键词
Oxidative dehydrogenation; ODH; mixed oxides; LDH;
D O I
暂无
中图分类号
学科分类号
摘要
Oxidative dehydrogenation ofn-butane and propene has been studied on six Mg−Al−Fe oxide catalysts prepared by thermal decomposition of layered double hydroxides with a hydrotalcite-like structure, possessing Mg2+ and Al3+ ions in the brucite-like layers, and hexacyanoferrate in the interlayers. In all cases, CO2 and H2O are formed, together with minor amounts of ethylene and methane. On the solids prepared from hexacyanoferrate(II), formation of benzene is also observed.
引用
收藏
页码:53 / 58
页数:5
相关论文
共 50 条
  • [1] Oxidation of n-butane and propene on exhydrotalcite Mg, Al, Fe mixed oxides
    Holgado, MJ
    San Roman, MS
    Rives, V
    REACTION KINETICS AND CATALYSIS LETTERS, 1998, 65 (01): : 53 - 58
  • [2] Characterization of Ni-Mg-Al mixed oxides and their catalytic activity in oxidative dehydrogenation of n-butane and propene
    Holgado, MJ
    Rives, V
    San Román, MS
    APPLIED CATALYSIS A-GENERAL, 2001, 214 (02) : 219 - 228
  • [4] Synthesis of Tunable-Acidity Vanadium Phosphorus Oxide CatalystsModified by Layered Double Oxide for the Selective Oxidation ofn-Butane
    Zhang, Huiling
    Dong, Jie
    Li, Yingwei
    Chen, Fan
    Zhang, Ruirui
    Xiang, Xu
    Liu, Ruixia
    He, Jing
    Zhang, Suojiang
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2022, 61 (11) : 3850 - 3859
  • [5] OXIDATION OF PROPENE ON MIXED OXIDES OF COPPER AND COBALT
    BAUSSART, H
    DELOBEL, R
    LEBRAS, M
    LEROY, JM
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1979, 75 : 1337 - 1345
  • [6] Propene oxidation and NO reduction over MgCu-Al(Fe) mixed oxides derived from hydrotalcite-like compounds
    Mrad, Raya
    Cousin, Renaud
    Poupin, Christophe
    Aboukais, Antoine
    Siffert, Stephane
    CATALYSIS TODAY, 2015, 257 : 98 - 103
  • [7] Selective catalytic oxidation of ammonia to nitrogen over Mg-Al, Cu-Mg-Al and Fe-Mg-Al mixed metal oxides doped with noble metals
    Chmielarz, Lucjan
    Jablonska, Magdalena
    Struminski, Adam
    Piwowarska, Zofia
    Wegrzyn, Agnieszka
    Witkowski, Stefan
    Michalik, Marek
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 130 : 152 - 162
  • [8] OXIDATION OF PROPENE ON A SB, SN, FE MIXED OXIDES CATALYST - MECHANISTIC STUDY WITH THERMAL PROGRAMMED DESORPTION
    PERRARD, A
    JOLY, JP
    GERMAIN, JE
    COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II, 1981, 293 (04): : 263 - 266
  • [9] Mg-Fe mixed oxides and their rehydrated mixed oxides as catalysts for transesterification
    Hajek, Martin
    Kocik, Jaroslav
    Frolich, Karel
    Vavra, Ales
    JOURNAL OF CLEANER PRODUCTION, 2017, 161 : 1423 - 1431
  • [10] STUDIES OF PROPENE OXIDATION OVER MIXED URANIUM-ANTIMONY OXIDES
    FARRELL, FJ
    NEVELL, TG
    HUCKNALL, DJ
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 : 3587 - 3600